Citation: Li-Zhuang Chen, Deng-Deng Huang. Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4, 5-dicarboxylate[J]. Chinese Chemical Letters, ;2014, 25(2): 279-282. shu

Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4, 5-dicarboxylate

Li-Zhuang Chen ^, ,
Deng-Deng Huang

1.
School of Biology and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: Li-Zhuang Chen,
Received Date: 22 October 2013
Available Online: 11 November 2013
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21201087) (No. 21201087) and sponsored by Qing Lan Project of Jiangsu Province. (No. 11KJB150004)

A new Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate (H₃PIDC) has been synthesized under hydrothermal conditions, formulated as {[Gd₃(HPIDC)₃(PIDC)(H₂O)₄]·3H₂O}_n (1). The compound crystallizes in the monoclinic system, space group C2/c with a = 20.951(7), b = 9.515(3), c = 27.483(10)Å, β = 106.176(6)°, Z = 4, V = 5262(3)Å³, C₄₀H₄₅Gd₃N₁₂O₃₀, D_c = 2.071 g/cm³, M_r = 1645.63, λ (MoKa) = 0.71073Å, μ = 3.846 mm^-1, F(000) = 3204, the final R = 0.0390 and wR = 0.1332. Complex 1 is a two-dimensional MOF built up from T-shaped 3-connected HPIDC^2-, PIDC^3- and 4-connected metal nodes. Dielectric constant of complex 1 was measured at different frequencies with temperature variation.
- 2D network,
- 2-(Pyridin-4-yl)-1H-imidazole-4,5-,
- dicarboxylate,
- Gd coordination polymer,
- Dielectric constant
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