Citation: Yi-Lin Wu, Yong-Sheng Yan, Jian-Ming Pan, Xiao-Hui Dai, Wei-Dong Shi, Min-Jia Meng. Fabrication and evaluation of molecularly imprinted regenerated cellulose composite membranes via atom transfer radical polymerization[J]. Chinese Chemical Letters, ;2014, 25(2): 273-278. shu

Fabrication and evaluation of molecularly imprinted regenerated cellulose composite membranes via atom transfer radical polymerization

1.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: Yong-Sheng Yan,
Received Date: 11 October 2013
Available Online: 1 November 2013
Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 21077046, 21107037, 21176107, 21174057, 2100403, 21207051) (Nos. 21077046, 21107037, 21176107, 21174057, 2100403, 21207051) National key basic research development program (973 Program, No. 2012CBB21500) (973 Program, No. 2012CBB21500) Ph.D. Programs Foundation of Ministry of Education of China (No. 20123227120015) (No. 20123227120015)Natural Science Foundation of Jiangsu Province (Nos. BK2011461, SBK2011459, BK2011514). China Postdoctoral Science Foundation funded project (Nos. 2012M511220, 2013M530240). (Nos. BK2011461, SBK2011459, BK2011514)

A simple and effective method for surface molecularly imprinted composite membranes (MICMs) for artemisinin (Ars) based on regenerated cellulose membranes was first prepared through surfaceinitiated atom transfer radical polymerization (ATRP), and the as-prepared MICMs were then evaluated as adsorbents for selective recognition and separation of Ars molecules. Batch rebinding studies were conducted to determine the specific adsorption equilibrium, kinetics and selective permeation performance. The adsorption capacity of MICMs toward Ars by the Langmuir isotherm model was 2.008 mg g^-1, which was nearly 5.0 times higher than non-molecularly imprinted composite membranes (NICMs). The kinetic property of MICMs was well-fitted by the pseudo-second-order rate equation. The selective permeation experiments were successfully investigated to prove the excellent selective permeation performance for Ars than the competitive analog (artemether).
- Molecularly imprinted composite,
- membranes,
- Atom transfer radical polymerization,
- Selective recognition,
- Artemisinin
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沈阳化工大学材料科学与工程学院沈阳 110142