Citation: Xing-Wei Wang, Hui Guo, Meng-Jie Liu, Xin-Yi Wang, Dong-Sheng Deng. 2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property[J]. Chinese Chemical Letters, ;2014, 25(2): 243-246. shu

2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property

Xing-Wei Wang ^a,b ,
Hui Guo ^b ,
Meng-Jie Liu ^a,b ,
Xin-Yi Wang ^a,, ,
Dong-Sheng Deng ^a,b,,

1.
a Institute of Resources & Environment, Henan Polytechnic University, Jiaozuo 454150, China;
2.
b College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: Xin-Yi Wang, Dong-Sheng Deng,
Received Date: 29 July 2013
Available Online: 8 November 2013
Fund Project: We gratefully acknowledge the financial support from the National Natural Science Foundation of China (No.21272109) (No.21272109) the Natural Science Foundation of Henan Province (No.112300410138) (No.112300410138) and Luoyang Science and Technology Fund. (No.2011B150021)

A new 2D coordination polymer, [Cd(tpim)(1,5-nds)]_n(1), was constructed from 1,5-naphthalenedisulfonate (1,5-nds), 2,4,5-tri(4-pyridyl)-imidazole (tpim) and Cd(CH₃COO)₂·2H₂O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of 1 in the solid state were also investigated.
- Crystal structure,
- Organosulfonate,
- Coordination polymer,
- Epoxide ring-opening
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