Citation: Jing-Hui Lyu, Xiao-Bo He, Chun-Shan Lu, Lei Ma, Qun-Feng Zhang, Feng Feng, Xiao-Nian Li, Jian-Guo Wang. The promoting role of minor amount of water in solvent-free hydrogenation of halogenated nitrobenzenes[J]. Chinese Chemical Letters, ;2014, 25(2): 205-208. shu

The promoting role of minor amount of water in solvent-free hydrogenation of halogenated nitrobenzenes

1.
Institute of Industrial Catalysis, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, China

Corresponding author: Xiao-Nian Li, Jian-Guo Wang,
Received Date: 7 September 2013
Available Online: 10 October 2013
Fund Project: Zhejiang Provincial Natural Science Foundation of China (No. LY12B03005). (973 Program)

This study shows that minor amount of water plays a very important role in solvent-free hydrogenation of halogenated nitrobenzenes. For dried sponge Pd, the reaction cannot occur in the absence of water. For Pd/C catalyst, minor amount of water reduces the induction time, increases the reaction rate and reaction TOFs. Water might enhance the diffusion, adsorption and dissociation of H₂ on Pd catalysts.
- Halogenated nitrobenzenes,
- Solvent free,
- Water,
- Hydrogenation
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沈阳化工大学材料科学与工程学院沈阳 110142