Citation: Yu-Jun Si, Zhong-Ping Xiong, Chang-Guo Chen, Ping Liu, Hui-Juan Wu. A non-precious metal catalyst for oxygen reduction prepared by heat-treating a mechanical mixture of carbon black, melamine and cobalt chloride[J]. Chinese Chemical Letters, ;2013, 24(12): 1109-1111. shu

A non-precious metal catalyst for oxygen reduction prepared by heat-treating a mechanical mixture of carbon black, melamine and cobalt chloride

1.
a College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science and Engineering, Zigong 643000, China;
2.
b College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China

Corresponding author: Yu-Jun Si, Chang-Guo Chen,
Received Date: 19 June 2013
Available Online: 24 July 2013
Fund Project: This work was supported by the Fundamental Research Funds for the Central Universities (No. CDJXS12220002) (No. CDJXS12220002) the Opening Project of Key Laboratory of Green Catalysis of Sichuan Institutes of High Education (No. LYJ1206) (No. 2012RC16) the National Undergraduate Innovation Training Project (No. 1110611046) (No. LYJ1206)Discipline Construction Project of Sichuan University of Science and Engineering. (No. 1110611046)

A non-precious metal catalyst CoMe/C for the oxygen reduction reaction is prepared by heat-treating a mechanical mixture of carbon black,melamine and cobalt chloride at 600 under nitrogen atmosphere for 2 h. The catalytic activity of CoMe/C is characterized by the electrochemical linear swee_p voltammetry technique. The onset reduction potential of the catalyst is 0.55 V (vs. SCE) at a scanning rate of 5 mV/s in 0.5 mol/L H₂SO₄ solution. The formation of the ORR activity sites of CoMe/C is facilitated by metallic β-cobalt.
- Oxygen reduction,
- Non-precious metal catalyst,
- Preparation,
- Mechanical method
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沈阳化工大学材料科学与工程学院沈阳 110142