Citation: Yue-Jun Ouyang, Yuan-Yuan Li, Ning-Bo Li, Xin-Hua Xu. A simple and convenient method for the synthesis of S-aryl phosphorothioates catalyzed by cesium hydroxide[J]. Chinese Chemical Letters, ;2013, 24(12): 1103-1105. shu

A simple and convenient method for the synthesis of S-aryl phosphorothioates catalyzed by cesium hydroxide

1.
a Department of Chemistry and Chemical Engineering, Huaihua University, Huaihua 418000, China;
2.
b College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

Corresponding author: Xin-Hua Xu,
Received Date: 3 May 2013
Available Online: 8 June 2013
Fund Project: The project was supported by the National Nature Science Foundation of China (Nos. 21273068, 21172061, J1210040). (Nos. 21273068, 21172061, J1210040)

In the presence of a catalytic amount of cesium hydroxide, the corresponding S-aryl phosphorothioates can be obtained by the reactions of dialkyl phosphites with diaryldisulfides in excellent yields at room temperature, using DMSO as a solvent. The reaction mechanism was discussed. The method provides a new and expedient path for the preparation of S-aryl phosphorothioates.
- Cesium hydroxide,
- Diaryldisulfides,
- O,O-Dialkyl-S-arylphosphorothioates
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