Citation: Shu Sun, Jian-Bing Shi, Yu-Ping Dong, Chen Lin, Xiao-Yu Hub, Le-Yong Wang. A pillar[5]arene-based side-chain pseudorotaxanes and polypseudorotaxanes as novel fluorescent sensors for the selective detection of halogen ions[J]. Chinese Chemical Letters, ;2013, 24(11): 987-992. shu

A pillar[5]arene-based side-chain pseudorotaxanes and polypseudorotaxanes as novel fluorescent sensors for the selective detection of halogen ions

Shu Sun ^a,b ,
Jian-Bing Shi ^a ,
Yu-Ping Dong ^a ,
Chen Lin ^b ,
Xiao-Yu Hub ^b,, ,
Le-Yong Wang ^b,,

1.
a School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
2.
b Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: Xiao-Yu Hub, Le-Yong Wang,
Received Date: 7 April 2013
Available Online: 26 June 2013

A pseudorotaxane and its polypseudorotaxanes formed between pillar[5]arene moieties and n-octylpyrazinium cations as novel fluorescent sensors for the selective detection of halogen ions were reported. A collapse of these pillar[5]arene-based pseudorotaxanes and polypseudorotaxanes occurred upon the addition of Cl^-, Br^-, and I^-(tetrabutylammonium salts), respectively, leading to their fluorescence recovery. The fluorescence enhancement of the pseudorotaxane and the polypseudorotaxanes increases in the order of I^-< Br^-< Cl^-, and the differences in fluorescence intensity could be easily distinguished by naked eyes under UV light illumination.
- Pillar[5]arene,
- Polypseudorotaxanes,
- Fluorescent sensor,
- Halogen ions detection
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