Citation: Li-Hua Wang, Zhi-Jun Zhang, Heng-Yi Zhang, Hai-Lang Wu, Yu Liu. A twin-axial[5]pseudorotaxane based on cucurbit[8]uril and a-cyclodextrin[J]. Chinese Chemical Letters, ;2013, 24(11): 949-952. shu

A twin-axial[5]pseudorotaxane based on cucurbit[8]uril and a-cyclodextrin

1.
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Yu Liu,
Received Date: 17 May 2013
Available Online: 14 June 2013

A twin-axial hetero[5]pseudorotaxane was constructed based on 1-hexyl-4,40-bipyridinium guest 1 and cucurbit[8]uril (CB[8]) and a-cyclodextrin (a-CD). In its structure, CB[8] included two bipyridinium units to realize the twin-axial mode, and the hexyl chain was threaded into the cavity of a-CD. The [5]pseudorotaxane contains two types of macrocyclic hosts while the single axial and twin axial modes co-exist in its structure. The transformation of [5]pseudorotaxane could be realized by the addition of acid and 2,6-dihydroxynaphthalene (HN).
- Pseudorotaxane,
- Cucurbituril,
- Cyclodextrin,
- Self-assembly
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