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Citation: Li-Li Ban, Ping Liu, Cun-Hua Ma, Bin Dai. Deep extractive desulfurization of diesel fuels by FeCl3/ionic liquids[J]. Chinese Chemical Letters, ;2013, 24(8): 755-758. shu

Deep extractive desulfurization of diesel fuels by FeCl3/ionic liquids

  • 1.

    School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China

  • Corresponding author: Bin Dai, 
  • Received Date: 21 January 2013
    Available Online: 12 April 2013

  • The extractive desulfurization of dibenzothiophene (DBT), benzothiophene (BT), and 4,6-dimethyldibenzothiophene (4,6-DMDBT) in model oil was carried out using anhydrous FeCl3 and 1-methyl-3-octylimidazolium chloride system ([Omim]Cl·2FeCl3). This new system exhibited high extractive efficiency and the sulfur removal of DBT in model oil (VIL/Voil = 1/20) could reach 99.4% at room temperature for 30 min, which was obviously superior to single [Omim]Cl as extractant (22.9%). When the [Omim]Cl·2FeCl3 was used, the S-removal of 4,6-DMDBT and BT could also be up to 99.3% and 96.2%, respectively. Moreover, the ionic liquid could be recycled five times without a significant decrease in extractive ability.
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    1. [1]

      [1] Y.W. Hu, Q.H. He, Z. Zhang, et al., Oxidative desulfurization of dibenzothiophene with hydrogen peroxide catalyzed by selenium(Ⅳ)-containing peroxotungstate, Chem. Commun. 47 (2011) 12194-12196.

    2. [2]

      [2] V.C. Srivastava, An evaluation of desulfurization technologies for sulfur removal from liquid fuels, RSC Adv. 2 (2012) 759-783.

    3. [3]

      [3] C. Sepulveda, V. Belliére, D. Laurenti, et al., Supported rhenium sulfide catalysts in thiophene and 4,6-dimethyldibenzothiophene hydrodesulfurization: effect of acidity of the support over activities, Appl. Catal. A: Gen. 393 (2011) 288-293.

    4. [4]

      [4] F.T. Li, R.H. Liu, J.H. Wen, et al., Desulfurization of dibenzothiophene by chemical oxidation and solvent extraction with Me3NCH2C6H5Cl32ZnCl2 ionic liquid, Green Chem. 11 (2009) 883-892.

    5. [5]

      [5] A. Seeberger, A. Jess, Desulfurization of diesel oil by selective oxidation and extraction of sulfur compounds by ionic liquids -a contribution to a competitive process design, Green Chem. 12 (2010) 602-608.

    6. [6]

      [6] L. Alonso, A. Arce, M. Francisco, et al., Measurement and correlation of liquid-liquid equilibria of two imidazolium ionic liquids with thiophene and methylcyclohexane, J. Chem. Eng. Data 52 (2007) 2409-3241.

    7. [7]

      [7] W.S. Zhu, J.T. Zhang, H.M. Li, et al., Fenton-like ionic liquids/H2O2 system: one-pot extraction combined with oxidation desulfurization of fuel, RSC Adv. 2 (2012) 658-664.

    8. [8]

      [8] C. Huang, B. Chen, J. Zhang, et al., Desulfurization of gasoline by extraction with new ionic liquids, Energy Fuels 18 (2004) 1862-1864.

    9. [9]

      [9] A. Bosmann, L. Datsevich, A. Jess, et al., Deep desulfurization of diesel fuel by extraction with ionic liquids, Chem. Commun. 23 (2001) 2494-2495.

    10. [10]

      [10] M. Wang, B. Li, C.J. Zhao, J. Korean, Recovery of [BMIM]FeCl4 from homogeneous mixture using a simple chemical method, Korean J. Chem. Eng. 27 (2010) 1275-1277.

    11. [11]

      [11] N.H. Ko, J.S. Lee, E.S. Huh, et al., Extractive desulfurization using Fe-containing ionic liquids, Energy Fuels 22 (2008) 1687-1690.

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