Citation: Kun-Huan He, Yun-Wu Li, Yong-Qiang Chen, Ze Chang. A new 8-connected self-penetrating metal-organic framework based on dinuclear cadmium clusters as secondary building units[J]. Chinese Chemical Letters, ;2013, 24(8): 691-694. shu

A new 8-connected self-penetrating metal-organic framework based on dinuclear cadmium clusters as secondary building units

1.
Department of Chemistry, and Tianjin Key Lab of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Ze Chang,
Received Date: 12 March 2013
Available Online: 16 April 2013

A new metal-organic framework (MOF) based on metal clusters as secondary building units (SBU), has been synthesized and structurally characterized. The reported MOF presents an interesting 8-connected self-penetrating coordination network based on dinuclear cadmium cluster with a 4²⁴·5·6³ topology. Moreover, the thermal stability and luminescence property of this compound have been investigated.
- Metal-organic framework,
- Secondary building units,
- Coordination network,
- Luminescence property
1. [1]
  [1] (a) M.C. Das, S.C. Xiang, Z.J. Zhang, B.L. Chen, Functional mixed metal-organic frameworks with metalloligands, Angew. Chem. Int. Ed. 50 (2011) 10510-10520;
2. [2]
  (b) F.N. Dai, H.Y. He, D.F. Sun, A metal-organic nanotube exhibiting reversible adsorption of (H₂O)₁₂ cluster, J. Am. Chem. Soc. 130 (2008) 14064-14065;
3. [3]
  (c) W.G. Lu, C.Y. Su, T.B. Lu, et al., Two stable 3D metal-organic frameworks constructed by nanoscale cages via sharing the single-layer walls, J. Am. Chem. Soc. 128 (2006) 34-35;
4. [4]
  (d) X.H. Bu, M.L. Tong, H.C. Chang, et al., A neutral 3D copper coordination polymer showing 1D open channels and the first interpenetrating NbO-type network, Angew. Chem. Int. Ed. 43 (2004) 192-195.
5. [5]
  [2] (a) M.D. Allendorf, C.A. Bauer, R.K. Bhakta, R.J.T. Houk, Luminescent metal-organic frameworks, Chem. Soc. Rev. 38 (2009) 1330-1352;
6. [6]
  (b) G.J. Halder, C.J. Kepert, B. Moubaraki, et al., Guest-dependent spin crossover in a nanoporous molecular framework material, Science 298 (2002) 1762-1765;
7. [7]
  (c) J.A. Zhao, L.W. Mi, J.Y. Hu, et al., Cation exchange induced tunable properties of a nanoporous octanuclear Cu(Ⅱ) wheel with double-helical structure, J. Am. Chem. Soc. 130 (2008) 15222-15223;
8. [8]
  (d) W.C. Song, Q. Pan, P.C. Song, et al., Two unprecedented 10-connected bct topological metal-organic frameworks constructed from cadmium clusters, Chem. Commun. 46 (2010) 4890-4892.
9. [9]
  [3] (a) M. O'Keeffe, O.M. Yaghi, Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets, Chem. Rev. 112 (2012) 675-702;
10. [10]
  (b) D.J. Tranchemontagne, J.L. Mendoza-Cortés, M. O'Keeffe, O.M. Yaghi, Secondary building units, nets and bonding in the chemistry of metal-organic frameworks, Chem. Soc. Rev. 38 (2009) 1257-1283.
11. [11]
  [4] (a) L.J. Murray, M. Dinc, J.R. Long, Hydrogen storage in metal-organic frameworks, Chem. Soc. Rev. 38 (2009) 1294-1314;
12. [12]
  (b) G. Férey, C. Serre, Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences, Chem. Soc. Rev. 38 (2009) 1380-1399.
13. [13]
  [5] (a) M. Du, Z.H. Zhang, Y.P. You, X.J. Zhao, R-Isophthalate (R = -H, -NO₂, and -COOH) as modular building blocks for mixed-ligand coordination polymers incorporated with a versatile connector 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole, CrystEngComm10 (2008) 306-321;
14. [14]
  (b) M. Du, Z.H. Zhang, L.F. Tang, et al., Molecular tectonics of metal-organic frameworks (MOFs) -a rational design strategy for unusual mixed-connected network topologies, Chem. Eur. J. 13 (2007) 2578-2586.
15. [15]
  [6] (a) Z.M. Hao, R.Q. Fang, H.S.Wu, X.M. Zhang, Cu₆S₄ cluster based twelve-connected face-centered cubic and Cu₁₉I₄S₁₂ cluster based fourteen-connected body-centered cubic topological coordination polymers, Inorg. Chem. 47 (2008) 8197-8203;
16. [16]
  (b) X.M. Zhang, R.Q. Fang, H.S. Wu, A twelve-connected Cu₆S₄ cluster-based coordination polymer, J. Am. Chem. Soc. 127 (2005) 7670-7671;
17. [17]
  (c) J.W. Cheng, S.T. Zheng, W. Liu, G.Y. Yang, An unusual eight-connected selfpenetrating ilc net constructed by dinuclear lanthanide building units, CrystEng-Comm^-10 (2008) 765-769.
18. [18]
  [7] (a) D.S. Li, F. Fu, J. Zhao, et al., Unique 3D self-penetrating Co^Ⅱ and Ni^Ⅱ coordination frameworks with a new (4⁴·6¹⁰·8) network topology, Dalton Trans. 39 (2010) 11522-11525;
19. [19]
  (b) J. Zhang, Y.G. Yao, X. Bu, A comparative study of homochiral and racemic chiral metal-organic frameworks built from camphoric acid, Chem. Mater. 19 (2007) 5083-5089;
20. [20]
  (c) D.L. Long, R.J. Hill, A.J. Blake, et al., Anion control over interpenetration and framework topology in coordination networks based on homoleptic six-connected scandium nodes, Chem. Eur. J. 11 (2005) 1384-1391;
21. [21]
  (d) J. Yang, J.F. Ma, Y.Y. Liu, S.R. Batten, Four-, and six-connected entangled frameworks based on flexible bis(imidazole) ligands and long dicarboxylate anions, CrystEngComm^-11 (2009) 151-159.
22. [22]
  [8] (a) S.R. Zheng, Q.Y. Yang, R. Yang, et al., Metal-directed assembly of coordination polymers with a multifunctional semirigid ligand containing pyridyl and benzimidazolyl donor groups, Cryst. Growth Des. 9 (2009) 2341-2353;
23. [23]
  (b) Y.Q. Wang, J.Y. Zhang, Q.X. Jia, et al., Unprecedented self-penetrating eightconnected network based on novel azide-bridged tetramanganese(Ⅱ) clusters, Inorg. Chem. 48 (2009) 789-791;
24. [24]
  (c) P.K. Chen, S.R. Batten, Y. Qi, J.M. Zheng, Two 3-D cluster-based frameworks: highly eight-connected molecular topology and magnetism, Cryst. Growth Des. 9 (2009) 2756-2761;
25. [25]
  (d) L.F. Ma, L.Y. Wang, Y.Y. Wang, et al., Self-assembly of a series of cobalt(Ⅱ) coordination polymers constructed from H2tbip and dipyridyl-based ligands, Inorg. Chem. 48 (2009) 915-924.
26. [26]
  [9] (a) J. Yang, B. Li, J.F. Ma, et al., An unusual ten-connected self-penetrating metal-organic framework based on tetranuclear cobalt clusters, Chem. Commun. (2010) 8383-8385;
27. [27]
  (b) D.R. Xiao, H.Y. Chen, G.J. Zhang, et al., An unprecedented (5,12)-connected 3D self-penetrating metal-organic framework based on dinuclear barium clusters as building blocks, CrystEngComm13 (2011) 433-436;
28. [28]
  (c) D.S. Li, Y.P. Wu, P. Zhang, et al., An unprecedented eight-connected selfpenetrating coordination framework based on cage-shaped [Pb₆(μ₄-O)₂(O₂C)₈] clusters, Cryst. Growth Des. 10 (2010) 2037-2040.
29. [29]
  [10] (a) Y.Q. Lan, X.L. Wang, S.L. Li, et al., An unprecedented (6,8)-connected selfpenetrating network based on two distinct zinc clusters, Chem. Commun. (2007) 4863-4865;
30. [30]
  (b) C. Qin, X.L. Wang, E.B. Wang, Z.M. Su, Catenation of loop-containing 2D layers with a 3D pcu skeleton into a new type of entangled framework having polyrotaxane and polycatenane character, Inorg. Chem. 47 (2008) 5555-5557;
31. [31]
  (c) Y.Q. Lan, S.L. Li, J.S. Qin, et al., Self-assembly of 2D→2D interpenetrating coordination polymers showing polyrotaxane- and polycatenane-like motifs: influence of various ligands on topological structural diversity, Inorg. Chem. 47 (2008) 10600-10610.
32. [32]
  [11] K.H. He, W.C. Song, Y.W. Li, et al., A new 10-connected coordination network with pentanuclear zinc clusters as secondary building units, Cryst. Growth Des. 12 (2012) 1064-1068.
33. [33]
  [12] (a) S. Zhang, J. Lan, Z. Mao, et al., Crystal water of cadmium acetate-dependent formation of one-dimensional channel structure based on 4,40-bis(1-imidazolyl) biphenyl, Cryst. Growth Des. 8 (2008) 3134-3136;
34. [34]
  (b) R.A. Altman, S.L. Buchwald, 4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed n-arylation of imidazoles, Org. Lett. 8 (2006) 2779-2782.
35. [35]
  [13] Crystallographic data for 1 (CCDC No. 882529): C₁₈H₁₁N₂O₄Cd, Mr = 431.7, monoclinic, C2/c, a = 16.851(3)Å, b = 15.092(3)Å, c = 13.455(3)Å, α= 90°, β= 118.25(3)Å, γ = 90°, V = 3014.2(6) Å³, Z = 4. rc = 1.903 cm^-3, μ = 1.476mm^-1, F(0 0 0) = 1704, S = 1.014, Rint = 0.0526 (for 2231 unique reflections), R1 = 0.0418 and wR2 = 0. 0678.
36. [36]
  [14] Q.R. Fang, G.S. Zhu, Z. Jin, et al., A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters, Angew. Chem. Int. Ed. 45 (2006) 6126-6130.
37. [37]
  [15] (a) V.A. Blatov, TOPOS 4.0 A Multipurpose Crystallochemical Analysis with the Program Package, Samara State University, Russia, 2004;
38. [38]
  (b) Reticular Chemistry Structure Resource (RCSR), http://rcs r.anu.edu.au/.
39. [39]
  [16] (a) X.J. Ke, D.S. Li, M. Du, Design and construction of self-penetrating coordination frameworks, Inorg. Chem. Commun. 14 (2011) 788-803;
40. [40]
  (b) F. Luo, J.M. Zheng, G.J. Long, Unique anionic eight-connected net with 3⁶4¹⁸5³6 topology derived from a rare Co₆(μ₃-OH)₂(μ-H₂O)·(CO₂)₁₂ building block, Cryst. Growth Des. 9 (2009) 1271-1274.
41. [41]
  [17] R.J. Hill, D.L. Long, N.R. Champness, et al., New approaches to the analysis of high connectivity materials: δesign frameworks based upon 44-and 63-subnet tectons, Acc. Chem. Res. 38 (2005) 337-348.
42. [42]
  [18] (a) S. Mizukami, H. Houjou, Y. Nagawa, M. Kanesato, First helical zinc(Ⅱ) complex with a salen ligand, Chem. Commun. (2003) 1148-1149;
43. [43]
  (b) J. Costa, R. Ruloff, L.S. Burai, et al., RigidM^ⅡL₂Gd₂^Ⅲ (M = Fe, Ru) complexes of a terpyridine-based heteroditopic chelate: a class of candidates for MRI contrast agents, J. Am. Chem. Soc. 127 (2005) 5147-5157.
44. [44]
  [19] (a) J. Tao, M.L. Tong, J.X. Shi, et al., Blue photoluminescent zinc coordination polymers with supertetranuclear cores, Chem. Commun. (2000) 2043-2044;
45. [45]
  (b) Z. Chang, A.S. Zhang, T.L. Hu, X.H. Bu, Zn(Ⅱ) coordination poylmers based on 2,3,6,7-anthracenetetracarboxylic acid: synthesis, structures, and luminescence properties, Cryst. Growth Des. 9 (2009) 4840-4846.
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