Citation: Hai-Yan Fu, Dong-Chen Huang, Tian-Ming Yang, Yuan-Bin She, Hao Zhang. Rapid recognition of Chinese herbal pieces of Areca catechu by different concocted processes using Fourier transform mid-infrared and near-infrared spectroscopy combined with partial least-squares discriminant analysis[J]. Chinese Chemical Letters, ;2013, 24(07): 639-642. shu

Rapid recognition of Chinese herbal pieces of Areca catechu by different concocted processes using Fourier transform mid-infrared and near-infrared spectroscopy combined with partial least-squares discriminant analysis

1.
a Third Class Laboratory About Ethno-medicine of State Administration of Traditional Chinese Medicine, College of Pharmacy, South-Central University for Nationalities, Wuhan 430074, China;
2.
b Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, China

Corresponding author: Tian-Ming Yang, Yuan-Bin She,
Received Date: 24 December 2012
Available Online: 8 April 2013

Rapid and sensitive recognition of herbal pieces according to different concocted processing is crucial to quality control and pharmaceutical effect. Near-infrared (NIR) and mid-infrared (MIR) technology combined with supervised pattern recognition based on partial least-squares discriminant analysis (PLSDA) was attempted to classify and recognize six different concocted processing pieces of 600 Areca catechu L. samples and the influence of fingerprint information preprocessing methods on recognition performance was also investigated in this work. Recognition rates of 99.24%, 100% and 99.49% for original fingerprint, multiple scatter correct (MSC) fingerprint and second derivative (2nd derivative) fingerprint of NIR spectra were achieved by PLSDA models, respectively. Meanwhile, a perfect recognition rate of 100% was obtained for the above three fingerprint models of MIR spectra. In conclusion, PLSDA can rapidly and effectively extract otherness of fingerprint information from NIR and MIR spectra to identify different concocted herbal pieces of A. catechu.
- NIR and MIR spectroscopy,
- Partial least-squares discriminant analysis,
- Different concocted processing herbal,
- pieces
1. [1]
  [1] R. Karoui, G. Downey, C. Blecker, Mid-infrared spectroscopy coupled with chemometrics: a tool for the analysis of intact food systems and the exploration of their molecular structure-quality relationships-a review, Chem. Rev. 110 (2010) 6144-6168.
2. [2]
  [2] J.J. Liu, H. Xu, W.S. Cai, et al., Discrimination of industrial products by on-line near infrared spectroscopy with an improved dendrogram, Chin. Chem. Lett. 22 (2011) 1241-1244.
3. [3]
  [3] Y. Wang, X. Ma, Y.D. Wen, et al., Discrimination of plant samples using nearinfrared spectroscopy with a principal component accumulation method, Anal. Methods 4 (2012) 2893-2899.
4. [4]
  [4] J.J. Liu, X. Ma, Y.D. Wen, et al., Online near-infrared spectroscopy combined with alternating trilinear decomposition for process analysis of industrial production and quality assurance, Ind. Eng. Chem. Res. 50 (2011) 7677-7681.
5. [5]
  [5] L. Reid, T. Woodcock, C.P. O' Donnell, et al., Differentiation of apple juice samples on the basis of heat treatment and variety using chemometric analysis of MIR and NIR data, Food Res. Int. 389 (2005) 1109-1115.
6. [6]
  [6] O. Galtier, O. Abbas, Y. Le Dréau, et al., Comparison of PLS1-DA, PLS2-DA and SIMCA for classification by origin of crude petroleum oils by MIR and virgin olive oils by NIR for different spectral regions, Vib. Spectrosc. 55 (2011) 132-140.
7. [7]
  [7] R. Riovanto, W.U. Cynkar, P. Berzaghi, et al., Discrimination between Shiraz wines from different Australian regions: the role of spectroscopy and chemometrics, J. Agric. Food Chem. 59 (2011) 10356-10360.
8. [8]
  [8] H.Y. Fu, S.Y. Huan, L. Xu, et al., Moving window partial least-squares discriminant analysis for identification of different kinds of bezoar samples by near infrared spectroscopy and comparison of different pattern recognition methods, J. Near. Infrared Spec. 15 (2007) 291-297.
9. [9]
  [9] S.M. van Ruth, B. Villegas, W. Akkermans, et al., Prediction of the identity of fats and oils by their fatty acid, triacylglycerol and volatile compositions using PLS-DA, Food Chem. 118 (2010) 948-955.
10. [10]
  [10] W.Q. Luo, S.Y. Huan, H.Y. Fu, et al., Preliminary study on the application of near infrared spectroscopy and pattern recognition methods to classify different types of apple samples, Food Chem. 128 (2011) 555-561.
11. [11]
  [11] U. Lutz, R.W. Lutz, W.K. Lutz, Metabolic profiling of glucuronides in human urine by LC-MS/MS and partial least-squares discriminant analysis for classification and prediction of gender, Anal. Chem. 78 (2006) 4564-4571.
12. [12]
  [12] P. Geladi, D. MacDougall, H. Martens, Linearization and scatter-correction for near-infrared reflectance spectra of meat, Appl. Spectrosc. 39 (1985) 491-500.
13. [13]
  [13] D.K. Holdsworth, R.A. Jones, R. Self, Volatile alkaloids from Areca catechu, Phytochemistry 48 (1998) 581-582.
14. [14]
  [14] A. Bales, M.J. Peterson, S. Ojha, K. Upadhaya, et al., Associations between betel nut (Areca catechu) and symptoms of schizophrenia among patients in Nepal: a longitudinal study, Psychiat. Res. 169 (2009) 203-211.
15. [15]
  [15] V. Ortiz-Somovilla, F. España-Españ a, A.J. Gaitán-Jurado, et al., Proximate analysis of homogenized and minced mass of pork sausages by NIRS, Food Chem. 101 (2007) 1031-1040.
16. [16]
  [16] Y.P. Zhou, J.H. Jiang, H.L. Wu, et al., Dry film method with ytterbium as the internal standard for near infrared spectroscopic plasma glucose assay coupled with boosting support vector regression, J. Chemometr. 20 (2006) 13-21.
1. [1]
  Yuyang Zhou , Ziwang Mao , Jing-Juan Xu . Recent advances in near infrared (NIR) electrochemiluminescence luminophores. Chinese Chemical Letters, 2024, 35(11): 109622-. doi: 10.1016/j.cclet.2024.109622
2. [2]
  Ling-Hao Zhao , Hai-Wei Yan , Jian-Shuang Jiang , Xu Zhang , Xiang Yuan , Ya-Nan Yang , Pei-Cheng Zhang . Effective assignment of positional isomers in dimeric shikonin and its analogs by ¹H NMR spectroscopy. Chinese Chemical Letters, 2024, 35(5): 108863-. doi: 10.1016/j.cclet.2023.108863
3. [3]
  Chengde Wang , Liping Huang , Shanshan Wang , Lihao Wu , Yi Wang , Jun Dong . A distinction of gliomas at cellular and tissue level by surface-enhanced Raman scattering spectroscopy. Chinese Chemical Letters, 2024, 35(5): 109383-. doi: 10.1016/j.cclet.2023.109383
4. [4]
  Manyu Zhu , Fei Liang , Lie Wu , Zihao Li , Chen Wang , Shule Liu , Xiue Jiang . Revealing the difference of Stark tuning rate between interface and bulk by surface-enhanced infrared absorption spectroscopy. Chinese Chemical Letters, 2025, 36(2): 109962-. doi: 10.1016/j.cclet.2024.109962
5. [5]
  Rakesh Kumar Gupta , Zhi Wang , Di Sun . Shining bright: Revolutionary near-unity NIR phosphorescent metal nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(11): 100417-100417. doi: 10.1016/j.cjsc.2024.100417
6. [6]
  Ruonan Guo , Heng Zhang , Changsheng Guo , Ningqing Lv , Beidou Xi , Jian Xu . Degradation of neonicotinoids with different molecular structures in heterogeneous peroxymonosulfate activation system through different oxidation pathways. Chinese Chemical Letters, 2024, 35(9): 109413-. doi: 10.1016/j.cclet.2023.109413
7. [7]
  Hui-Juan Wang , Wen-Wen Xing , Zhen-Hai Yu , Yong-Xue Li , Heng-Yi Zhang , Qilin Yu , Hongjie Zhu , Yao-Yao Wang , Yu Liu . Cucurbit[7]uril confined phenothiazine bridged bis(bromophenyl pyridine) activated NIR luminescence for lysosome imaging. Chinese Chemical Letters, 2024, 35(6): 109183-. doi: 10.1016/j.cclet.2023.109183
8. [8]
  Ji Liu , Dongsheng He , Tianjiao Hao , Yumin Hu , Yan Zhao , Zhen Li , Chang Liu , Daquan Chen , Qiyue Wang , Xiaofei Xin , Yan Shen . Gold mineralized "hybrid nanozyme bomb" for NIR-II triggered tumor effective permeation and cocktail therapy. Chinese Chemical Letters, 2024, 35(9): 109296-. doi: 10.1016/j.cclet.2023.109296
9. [9]
  Biao Huang , Tao Tang , Fushou Liu , Shi-Hui Chen , Zhi-Ling Zhang , Mingxi Zhang , Ran Cui . Quantum dots boost large-view NIR-Ⅱ imaging with high fidelity for fluorescence-guided tumor surgery. Chinese Chemical Letters, 2024, 35(12): 109694-. doi: 10.1016/j.cclet.2024.109694
10. [10]
  Lulu Cao , Yikun Li , Dongxiang Zhang , Shuai Yue , Rong Shang , Xin-Dong Jiang , Jianjun Du . Engineering aggregates of julolidine-substituted aza-BODIPY nanoparticles for NIR-II photothermal therapy. Chinese Chemical Letters, 2024, 35(12): 109735-. doi: 10.1016/j.cclet.2024.109735
11. [11]
  Xiaoshuai Wu , Bailei Wang , Yichen Li , Xiaoxuan Guan , Mingjing Yin , Wenquan Lv , Yin Chen , Fei Lu , Tao Qin , Huyang Gao , Weiqian Jin , Yifu Huang , Cuiping Li , Ming Gao , Junyu Lu . NIR driven catalytic enhanced acute lung injury therapy by using polydopamine@Co nanozyme via scavenging ROS. Chinese Chemical Letters, 2025, 36(2): 110211-. doi: 10.1016/j.cclet.2024.110211
12. [12]
  Du Liu , Yuyan Li , Hankun Zhang , Benhua Wang , Chaoyi Yao , Minhuan Lan , Zhanhong Yang , Xiangzhi Song . Three-in-one erlotinib-modified NIR photosensitizer for fluorescence imaging and synergistic chemo-photodynamic therapy. Chinese Chemical Letters, 2025, 36(2): 109910-. doi: 10.1016/j.cclet.2024.109910
13. [13]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
14. [14]
  Songtao Cai , Liuying Wu , Yuan Li , Soham Samanta , Jinying Wang , Bing Liu , Feihu Wu , Kaitao Lai , Yingchao Liu , Junle Qu , Zhigang Yang . Intermolecular hydrogen-bonding as a robust tool toward significantly improving the photothermal conversion efficiency of a NIR-II squaraine dye. Chinese Chemical Letters, 2024, 35(4): 108599-. doi: 10.1016/j.cclet.2023.108599
15. [15]
  Jianqiu Li , Yi Zhang , Songen Liu , Jie Niu , Rong Zhang , Yong Chen , Yu Liu . Cucurbit[8]uril-based non-covalent heterodimer realized NIR cell imaging through topological transformation from nanowire to nanorod. Chinese Chemical Letters, 2024, 35(10): 109645-. doi: 10.1016/j.cclet.2024.109645
16. [16]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
17. [17]
  Zhaorui Song , Qiulian Hao , Bing Li , Yuwei Yuan , Shanshan Zhang , Yongkuan Suo , Hai-Hao Han , Zhen Cheng . NIR-Ⅱ fluorescence lateral flow immunosensor based on efficient energy transfer probe for point-of-care testing of tumor biomarkers. Chinese Chemical Letters, 2025, 36(1): 109834-. doi: 10.1016/j.cclet.2024.109834
18. [18]
  Shangqian Zhang , Jiaxuan Li , Xuan Hu , Zelong Chen , Junliang Dong , Chenhao Hu , Shuang Chao , Yinghua Lv , Yuxin Pei , Zhichao Pei . H₂S and NIR light-driven nanomotors induce disulfidptosis for targeted anticancer therapy by enhancing disruption of tumor metabolic symbiosis. Chinese Chemical Letters, 2025, 36(1): 110314-. doi: 10.1016/j.cclet.2024.110314
19. [19]
  Fuzheng Zhang , Chao Shi , Jiale Li , Fulin Jia , Xinyu Liu , Feiyang Li , Xinyu Bai , Qiuxia Li , Aihua Yuan , Guohua Xie . B-embedded narrowband pure near-infrared (NIR) phosphorescent iridium(Ⅲ) complexes and solution-processed OLED application. Chinese Chemical Letters, 2025, 36(1): 109596-. doi: 10.1016/j.cclet.2024.109596
20. [20]
  Xueling Yu , Lixing Fu , Tong Wang , Zhixin Liu , Na Niu , Ligang Chen . Multivariate chemical analysis: From sensors to sensor arrays. Chinese Chemical Letters, 2024, 35(7): 109167-. doi: 10.1016/j.cclet.2023.109167

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(709)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142