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Citation: Ying Zhang, Xin-Bao Han, Zhi-Ming Zhang, Zhu-Jun Liu, En-Bo Wang. A {Ni7} cluster-containing sandwich-type phosphotungstate functionalized by organic bisphosphonate ligands and its two-dimensional supramolecular structure[J]. Chinese Chemical Letters, ;2013, 24(07): 581-584. shu

A {Ni7} cluster-containing sandwich-type phosphotungstate functionalized by organic bisphosphonate ligands and its two-dimensional supramolecular structure

  • 1.

    Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

  • Corresponding author: Zhi-Ming Zhang,  En-Bo Wang, 
  • Received Date: 29 January 2013
    Available Online: 15 April 2013

  • A {Ni7} cluster-substituted sandwich-type phosphotungstate Na10(NH4)4[{(B-a-PW9O34)Ni4 (OH)(H2O)2(HAle)}2Ni]·22H2O (1) was synthesized using the conventional aqueous solution method. Compound 1 represents the first nickel-containing sandwich-type polyoxometalate functionalized by bisphosphonate ligands. Further, the sandwich-type polyoxoanions aggregated via the H-bonding interactions into a two-dimensional (2D) supramolecular framework.
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