Citation: Cai-Xia Ding, Chang-Hua He, Yong-Shu Xie. Syntheses and structures of tetranuclear Zn(Ⅱ) complexes with in situ generated macrocyclic Schiff base ligands： Applications in Zn²⁺ sensing[J]. Chinese Chemical Letters, ;2013, 24(6): 463-466. shu

Syntheses and structures of tetranuclear Zn(Ⅱ) complexes with in situ generated macrocyclic Schiff base ligands： Applications in Zn²⁺ sensing

1.
Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Yong-Shu Xie,
Received Date: 21 January 2013
Available Online: 12 March 2013

Three novel Zn(Ⅱ) complexes, [Zn₄L₁Cl₄]·3H₂O (1), [Zn₄L₂Cl₄]·2DMF (2) and [Zn₄L₃C_l4]·H₂O (3), have been synthesized and structurally characterized. In these complexes, interesting 32-membered dodecadentate macrocyclic ligands were generated in situ by ‘2 + 2’ type condensation reactions between a tetraamine and various dialdehydes. All the complexes are isostructurally tetranuclear Zn(Ⅱ) complexes, containing endogenous alkoxo and phenoxo bridges. Applications of themacrocyclic ligands as Zn²⁺ sensors have been investigated. Take H₄L¹ for example, it exhibits a 4-fold fluorescence enhancement upon the addition of 2 equiv. of Zn²⁺ in MeOH.
- Macrocyclic ligand,
- Schiff base,
- Zn(Ⅱ) complexes,
- Fluorescent enhancement,
- CHEF effect
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses and structures of tetranuclear Zn(Ⅱ) complexes with in situ generated macrocyclic Schiff base ligands： Applications in Zn2+ sensing

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通讯作者: 陈斌, bchen63@163.com

Syntheses and structures of tetranuclear Zn(Ⅱ) complexes with in situ generated macrocyclic Schiff base ligands： Applications in Zn²⁺ sensing