Citation: Hong-Yu Guo, Fa-Fu Yang, Zi-Yu Jiao, Jian-Rong Lin. Click synthesis and dye extraction properties of novel thiacalix[4]arene derivatives with triazolyl and hydrogen bonding groups[J]. Chinese Chemical Letters, ;2013, 24(6): 450-452. shu

Click synthesis and dye extraction properties of novel thiacalix[4]arene derivatives with triazolyl and hydrogen bonding groups

1.
a College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
2.
b Fujian Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China

Corresponding author: Fa-Fu Yang,
Received Date: 23 February 2013
Available Online: 22 March 2013

Using a click reaction between alkynylthiacalix[4]arene and ethyl 2-azidoacetate followed by an ammonolysis with ethanolamine, leucinol and hydrazine hydrate, respectively, three novel thiacalix[4]arene derivatives 4, 5 and 6 with triazolyl and hydrogen bonding groups (NH and OH) were synthesized in high yields. They exhibited excellent extraction capability for six anionic and cationic dyes. The flexible cavity, π-triazole rings and hydrogen bonding groups all play crucial roles in dye complexation.
- Thiacalix[4]arene,
- Synthesis,
- Click chemistry,
- Dye extraction
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