Citation: Jing-Wen Ran, Shao-Wen Liu, Peng Wua, Jun Pei. Efficient photocatalytic properties of a dinuclear iron complex with bis[2-hydroxybenzaldehyde]hydrazonate ligand[J]. Chinese Chemical Letters, ;2013, 24(05): 373-375. shu

Efficient photocatalytic properties of a dinuclear iron complex with bis[2-hydroxybenzaldehyde]hydrazonate ligand

Jing-Wen Ran ^a ,
Shao-Wen Liu ^a ,
Peng Wua ^a,, ,
Jun Pei ^b

1.
a Chemical Engineering College, Huanggang Normal University, Huanggang 438000, China;
2.
b Education Science and Technology College, Huanggang Normal University, Huanggang 438000, China

Corresponding author: Peng Wua,
Received Date: 13 December 2012
Available Online: 27 February 2013

A novel photooxidative system for degrading toxic organic pollutants is reported. A new complex of Fe₂L₃(L = bis[2-hydroxybenzaldehyde]hydrazone) synthesized can efficiently activate hydrogen peroxide (H₂O₂) to oxidize and mineralize the target complexes rhodamine B (RhB) and methyl orange (MO) in aqueous media under ambient temperature and normal pressure and with visible light irradiation.
- Synthesis,
- Catalysis,
- Degradation,
- Mechanism
1. [1]
  [1] S.S. Gupta, M. Stadler, C.A. Noser, et al., Rapid total destruction of chlorophenols by activated hydrogen peroxide, Science 296 (2002) 326-328.
2. [2]
  [2] Y.P. Huang, W.H. Ma, J. Li, et al., A novel β-CD-hemin complex photocatalyst for efficient degradation of organic pollutants at neutral pHs under visible irradiation, J. Phys. Chem. B 107 (2003) 9409-9414.
3. [3]
  [3] W.H. Ma, J. Li, X. Tao, et al., Efficient degradation of organic pollutants by dioxygen activated by resin-exchanged iron bipyridine under visible irradiation, Angew. Chem. Int. Ed. 42 (2003) 1029-1032.
4. [4]
  [4] X. Tao, W.H. Mao, T.Y. Zhang, J.C. Zhao, Efficient photooxidative degradation of organic compounds in the presence of iron tetrasulfophthalocyanine under visible light irradiation, Angew. Chem. Int. Ed. 40 (2001) 3014-3016.
5. [5]
  [5] H. Mo, D. Guo, C.Y. Duan, Y.T. Li, Q. Meng, A three-dimensional porous metal-organic framework [Fe₂L₃(DMF)₇(C₄H₁₀O)_0.5] constructed from triple-helices {L = bis[2, 4-dihydroxybenzaldehyde]hydrazone}, Dalton Trans. 2 (2002) 3422-3424.
6. [6]
  [6] M.O. Seung, N.H. David, L.H. Karen, E.D. Raymond, Valence-detrapping modes for electron transfer in the solid state of mixed-valence, oxo-centered, trinuclear iron acetate complexes: X-ray structure and physical data for [Fe₃O(O₂CCH₃)₆(4-Etpy)₃](4-Et-py), J. Am. Chem. Soc. 107 (1985) 8009-8018.
7. [7]
  [7] J.W. Ran, X.Y. Li, Q.D. Zhao, et al., Synthesis, structures and photocatalytic properties of a mononuclear copper complex with pyridine-carboxylato ligands, Inorg. Chem. Commun. 13 (2010) 526-528.
8. [8]
  [8] J.W. Ran, X.Y. Li, Q.D. Zhao, et al., High-efficient photooxidative degradation of dyes catalyzed by hetero-nuclear complex under light irradiation, Inorg. Chem. Commun. 13 (2010) 1527-1529.
9. [9]
  [9] J. Saroja, V. Manivannan, P. Chakraborty, S. Pal, A diiron(Ⅲ) complex containing N-N bridges. Synthesis, structure, and properties, Inorg. Chem. 34 (1995) 3099-3101.
10. [10]
  [10] A. Chanda, S.K. Khetan, D. Banerjee, et al., Total degradation of fenitrothion and other organophosphorus pesticides by catalytic oxidation employing Fe-TAML peroxide activators, J. Am. Chem. Soc. 128 (2006) 12058-12059.
11. [11]
  [11] Y.L. Nie, C. Hu, J.H. Qu, L. Zhou, X.X. Hu, Photoassisted degradation of azodyes over FeO_xH_2x-3/Fe⁰ in the presence of H₂O₂ at neutral pH Values, Environ. Sci. Technol. 41 (2007) 4715-4719.
12. [12]
  [12] J. Li, W.H. Ma, Y.P. Huang, M.M. Cheng, J.C. Zhao, A highly selective photooxidation approach using O₂ in water catalyzed by iron (Ⅱ) bipyridine complex supported on NaY zeolite, Chem. Commun. 3 (2003) 2214-2215.
13. [13]
  [13] Y.P. Huang, J. Li, W.H. Ma, M.M. Cheng, J.C. Zhao, Efficient H₂O₂ oxidation of organic pollutants catalyzed by supported iron sulfophenylporphyrin under visible light irradiation, J. Phys. Chem. B 108 (2004) 7263-7270.
14. [14]
  [14] S.H. Bossmann, E. Oliveros, S. Gob, New evidence against hydroxyl radicals as reactive intermediates in the thermal and photochemically enhanced fenton reactions, J. Phys. Chem. A 102 (1998) 5542-5550.
15. [15]
  [15] E. Solomon, Geometric and electronic structure/function correlations in nonheme iron enzymes, Chem. Rev. 100 (2000) 235-349.
1. [1]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
2. [2]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
3. [3]
  Jia Fu , Shilong Zhang , Lirong Liang , Chunyu Du , Zhenqiang Ye , Guangming Chen . PEDOT-based thermoelectric composites: Preparation, mechanism and applications. Chinese Chemical Letters, 2024, 35(9): 109804-. doi: 10.1016/j.cclet.2024.109804
4. [4]
  Yuqing Zhu , Haohao Chen , Li Wang , Liqun Ye , Houle Zhou , Qintian Peng , Huaiyong Zhu , Yingping Huang . Piezoelectric materials for pollutants degradation: State-of-the-art accomplishments and prospects. Chinese Chemical Letters, 2024, 35(4): 108884-. doi: 10.1016/j.cclet.2023.108884
5. [5]
  Menglu Guo , Ying-Qi Song , Junfei Cheng , Guoqiang Dong , Xun Sun , Chunquan Sheng . Hydrophobic tagging-induced degradation of NAMPT in leukemia cells. Chinese Chemical Letters, 2024, 35(9): 109392-. doi: 10.1016/j.cclet.2023.109392
6. [6]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
7. [7]
  Shuai Li , Liuting Zhang , Fuying Wu , Yiqun Jiang , Xuebin Yu . Efficient catalysis of FeNiCu-based multi-site alloys on magnesium-hydride for solid-state hydrogen storage. Chinese Chemical Letters, 2025, 36(1): 109566-. doi: 10.1016/j.cclet.2024.109566
8. [8]
  Linghui Zou , Meng Cheng , Kaili Hu , Jianfang Feng , Liangxing Tu . Vesicular drug delivery systems for oral absorption enhancement. Chinese Chemical Letters, 2024, 35(7): 109129-. doi: 10.1016/j.cclet.2023.109129
9. [9]
  Yulong Shi , Fenbei Chen , Mengyuan Wu , Xin Zhang , Runze Meng , Kun Wang , Yan Wang , Yuheng Mei , Qionglu Duan , Yinghong Li , Rongmei Gao , Yuhuan Li , Hongbin Deng , Jiandong Jiang , Yanxiang Wang , Danqing Song . Chemical construction and anti-HCoV-OC43 evaluation of novel 10,12-disubstituted aloperine derivatives as dual cofactor inhibitors of TMPRSS2 and SR-B1. Chinese Chemical Letters, 2024, 35(5): 108792-. doi: 10.1016/j.cclet.2023.108792
10. [10]
  Zimo Yang , Yan Tong , Yongbo Liu , Qianlong Liu , Zhihao Ni , Yuna He , Yu Rao . Developing selective PI3K degraders to modulate both kinase and non-kinase functions. Chinese Chemical Letters, 2024, 35(11): 109577-. doi: 10.1016/j.cclet.2024.109577
11. [11]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
12. [12]
  Xiaoning Li , Quanyu Shi , Meng Li , Ningxin Song , Yumeng Xiao , Huining Xiao , Tony D. James , Lei Feng . Functionalization of cellulose carbon dots with different elements (N, B and S) for mercury ion detection and anti-counterfeit applications. Chinese Chemical Letters, 2024, 35(7): 109021-. doi: 10.1016/j.cclet.2023.109021
13. [13]
  Shaojie Deng , Peihua Ma , Qinghong Bai , Xin Xiao . The transformation of nor-seco-cucurbit[10]uril to cucurbit[5]uril and cucurbit[8]uril controlled by its own concentration. Chinese Chemical Letters, 2025, 36(2): 109878-. doi: 10.1016/j.cclet.2024.109878
14. [14]
  Weidan Meng , Yanbo Zhou , Yi Zhou . Green innovation unleashed: Harnessing tungsten-based nanomaterials for catalyzing solar-driven carbon dioxide conversion. Chinese Chemical Letters, 2025, 36(2): 109961-. doi: 10.1016/j.cclet.2024.109961
15. [15]
  Ming-Yi Sun , Lu Zhang , Ya Li , Chong-Chen Wang , Peng Wang , Xueying Ren , Xiao-Hong Yi . Recovering Ag⁺ with nano-MOF-303 to form Ag/AgCl/MOF-303 photocatalyst: The role of stored Cl⁻ ions. Chinese Chemical Letters, 2025, 36(2): 110035-. doi: 10.1016/j.cclet.2024.110035
16. [16]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
17. [17]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
18. [18]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
19. [19]
  Manoj Kumar Sarangi , L․D Patel , Goutam Rath , Sitansu Sekhar Nanda , Dong Kee Yi . Metal organic framework modulated nanozymes tailored with their biomedical approaches. Chinese Chemical Letters, 2024, 35(11): 109381-. doi: 10.1016/j.cclet.2023.109381
20. [20]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(566)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142