Citation: Bing Zhao, Ya-Cui Zhou, Meng-Jiao Fan, Zhi-Yu Li, Li-Yan Wang, Qi-Gang Deng. Synthesis, fluorescence properties and selective Cr(Ⅲ) recognition of tetraaryl imidazole derivatives bearing thiazole group[J]. Chinese Chemical Letters, ;2013, 24(3): 257-259. shu

Synthesis, fluorescence properties and selective Cr(Ⅲ) recognition of tetraaryl imidazole derivatives bearing thiazole group

1.
Chemistry and Chemical Engineering Institute, Qiqihar University, Qiqihar 161006, China

Corresponding author: Bing Zhao,
Received Date: 28 November 2012
Available Online: 5 January 2013

Three tetraaryl imidazole derivatives 5a-5c bearing thiazole groups were synthesized in the presence of [Bmin]Br by one-pot reaction and their structures were fully characterized by the ¹H NMR, IR, MS and elemental analysis. The results of UV-vis spectra and fluorescent spectra upon metal ions complexation show that compound 5a displays high selectivity and sensitivity for Cr³⁺ ions. The complexation ratio of compound 5a and Cr³⁺ is 1:1.
- Tetraaryl imidazole,
- Thiazole,
- Fluorescent,
- Selectivity Cr³⁺
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沈阳化工大学材料科学与工程学院沈阳 110142