Citation:
Ping Qiu, Yong-Nian Ni, Serge Kokot. Application of artificial neural networks to the determination of pesticides by linear sweep stripping voltammetry[J]. Chinese Chemical Letters,
;2013, 24(3): 246-248.
-
In this work, artificial neural network (ANN), a powerful chemometrics approach for linear and nonlinear calibration models, was applied to detect three pesticides in mixtures by linear sweep stripping voltammetry (LSSV) despite their overlapped voltammograms. Electrochemical parameters for the voltammetry, such as scan rate, deposit time and deposit potential, were evaluated and optimized from the signal response data using ANN model by minimizing the relative prediction error (RPE). The proposed method was successfully applied to the detection of pesticides in synthetic samples and several commercial fruit samples.
-
-
-
[1]
[1] E.M. Garrido, C. Delerue-Matos, J.L.F.C. Lima, A.M.O. Brett, Electrochemical methods in pesticides control, Anal. Lett. 37 (2004) 1755-1791.
-
[2]
[2] D.B. Barr, L.L. Needham, Analytical methods for biological monitoring of exposure to pesticides: a review, J. Chromatogr. B 778 (2002) 5-9.
-
[3]
[3] R.R. Kesari, V.K. Gupta, A sensitive spectrophotometric method for the determination of dithiocarbamate fungicide and its application in environmental samples, Talanta 45 (1998) 1097-1102.
-
[4]
[4] V.K. Sharma, J.S. Aulakh, A.K. Malik, Fourth derivative spectrophotometric determination of fungicide thiram (tetramethyl thiuram disulphide) in a commercial sample and grains using MIBK, Talanta 65 (2005) 375-379.
-
[5]
[5] D.A. Lambropoulou, I.K. Lonstantinou, T.A. Albanis, Determination of fungicides in natural waters using solid phase microextraction (SPME) and gas chromatography coupled with electron capture and mass spectrometric detection, J. Chromatogr. A 893 (2000) 143-156.
-
[6]
[6] Z.M. Liu, X.H. Zang, W.H. Liu, C. Wang, Z. Wang, Novel method for the determination of five carbamate pesticides in water samples by dispersive liquid-liquid microextraction combined with high performance liquid chromatography, Chin. Chem. Lett. 20 (2009) 213-216.
-
[7]
[7] C.M. Torres, Y. Pico, M.J. Redondo, J. Manes, Matrix solid phase dispersion extraction procedure for multiresidue pesticide analysis in oranges, J. Chromatogr. A 719 (1996) 95-103.
-
[8]
[8] S.P. Zhang, L.G. Shan, Z.R. Tian, et al., Study of enzyme biosensor based on carbon nanotubes modified electrode for detection of pesticides residue, Chin. Chem. Lett. 19 (2008) 592-594.
-
[9]
[9] J.N. Miller, J.C. Miller, Statistics and Chemometrics for Analytical Chemistry, 4th ed., Pearson Education Limited, London, 2000, pp. 122-126.
-
[10]
[10] Y.N. Ni, P. Qiu, S. Kokot, Simultaneous determination of three organophosphorus pesticides by differential pulse stripping voltammetry and chemometrics, Anal. Chim. Acta 516 (2004) 7-17.
-
[11]
[11] D.S. Broomhead, D. Lowe, Multivariable functional interpolation and adaptive networks, Complex Syst. 2 (1988) 321-355.
-
[12]
[12] Y.N. Ni, G.W. Zhang, S. Kokot, Simultaneous spectrophotometric determination of maltol, ethyl maltol, vanillin and ethyl vanillin in foods by multivariate calibration and artificial neural networks, Food Chem. 89 (2005) 465-473.
-
[13]
[13] M. Stone, Cross-validatory choice and assessment of statistical predictions, J. R. Statist. Soc. B 36 (1974) 111-147.
-
[14]
[14] B. Hemmateenejad, M. Akhond, R. Miri, M. Shamsipur, Genetic algorithm applied to the selection of factors in principal component-artificial neural networks: application to QSAR study of calcium channel antagonist activity of 1,4-dihydropyridines (nifedipine analogous), J. Chem. Inf. Comput. Sci. 43 (2003) 1328-1334.
-
[1]
-
-
-
[1]
Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
-
[2]
Feihu Wu , Gengwen Chen , Kaitao Lai , Shiqing Zhang , Yingchao Liu , Ruijian Luo , Xiaocong Wang , Pinzhi Cao , Yi Ye , Jiarong Lian , Junle Qu , Zhigang Yang , Xiaojun Peng . Non-specific/specific SERS spectra concatenation for precise bacteria classifications with few samples using a residual neural network. Chinese Chemical Letters, 2025, 36(1): 109884-. doi: 10.1016/j.cclet.2024.109884
-
[3]
Xinyu Liu , Jialin Yang , Zonglin He , Jiaoyan Ai , Lina Song , Baohua Liu . Linear polyurethanes with excellent comprehensive properties from poly(ethylene carbonate) diol. Chinese Chemical Letters, 2025, 36(1): 110236-. doi: 10.1016/j.cclet.2024.110236
-
[4]
Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
-
[5]
Meng Shan , Yongmei Yu , Mengli Sun , Shuping Yang , Mengqi Wang , Bo Zhu , Junbiao Chang . Bifunctional organocatalyst-catalyzed dynamic kinetic resolution of hemiketals for synthesis of chiral ketals via hydrogen bonding control. Chinese Chemical Letters, 2025, 36(1): 109781-. doi: 10.1016/j.cclet.2024.109781
-
[6]
Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
-
[7]
Peizhe Li , Qiaoling Liu , Mengyu Pei , Yuci Gan , Yan Gong , Chuchen Gong , Pei Wang , Mingsong Wang , Xiansong Wang , Da-Peng Yang , Bo Liang , Guangyu Ji . Chlorogenic acid supported strontium polyphenol networks ensemble microneedle patch to promote diabetic wound healing. Chinese Chemical Letters, 2024, 35(8): 109457-. doi: 10.1016/j.cclet.2023.109457
-
[8]
Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
-
[9]
Yunxin Li , Jinghui Zhang , Jisen Chen , Feng Zhu , Zhiqiang Liu , Peng Bao , Wei Shen , Sheng Tang . Detection of SARS-CoV-2 based on artificial intelligence-assisted smartphone: A review. Chinese Chemical Letters, 2024, 35(7): 109220-. doi: 10.1016/j.cclet.2023.109220
-
[10]
Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
-
[11]
Lei Zhou , Youjun Zhou , Lizhen Fang , Yiqiao Bai , Yujia Meng , Liang Li , Jie Yang , Yong Yao . Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications. Chinese Chemical Letters, 2024, 35(9): 109509-. doi: 10.1016/j.cclet.2024.109509
-
[12]
Shangda Qu , Yiming Yuan , Xu Ye , Wentao Xu . High sensitivity artificial synapses using printed high-transmittance ITO fibers for neuromorphic computing. Chinese Chemical Letters, 2024, 35(12): 110030-. doi: 10.1016/j.cclet.2024.110030
-
[13]
Ran Cen , Yan-Yan Tang , Li-Xia Chen , Zhu Tao , Xin Xiao . A novel supramolecular assembly based on nor-seco-cucurbit[10]uril for spermine sensing and artificial light-harvesting. Chinese Chemical Letters, 2025, 36(1): 109744-. doi: 10.1016/j.cclet.2024.109744
-
[14]
Brandon Bishop , Shaofeng Huang , Hongxuan Chen , Haijia Yu , Hai Long , Jingshi Shen , Wei Zhang . Artificial transmembrane channel constructed from shape-persistent covalent organic molecular cages capable of ion and small molecule transport. Chinese Chemical Letters, 2024, 35(11): 109966-. doi: 10.1016/j.cclet.2024.109966
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(608)
- HTML views(11)