Citation: Zi-Yong Li, Wen Xue, Guo-Xing Liu, Di Wu, Ting-Ting Li, Sheng-Hua Liu, Jun Yin. Synthesis and properties of template-promoted switchable dithienylethenebased macrocycles[J]. Chinese Chemical Letters, ;2013, 24(3): 189-191. shu

Synthesis and properties of template-promoted switchable dithienylethenebased macrocycles

Zi-Yong Li ^a ,
Wen Xue ^a ,
Guo-Xing Liu ^a ,
Di Wu ^a ,
Ting-Ting Li ^b ,
Sheng-Hua Liu ^a ,
Jun Yin ^a,,

1.
a Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China;
2.
b Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430079, China

Corresponding author: Jun Yin,
Received Date: 4 January 2013
Available Online: 26 January 2013

Three switchable macrocycles based on photochromic dithienylethene were synthesized under the template of dibenzylammonium hexafluorophosphate. Their structure were well-confirmed by NMR, ESI-MS and X-ray diffraction. Their photochromism indicated that they showed good reversibility in solution. Additionally, the theoretical calculation suggested that photoirradiation can change the cavity of macrocycles.
- Dithienylethene,
- Photochromism,
- Switchable macrocycle,
- Template synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142