Citation: Ying-Xiao Zong, Jun-Ke Wang, Yu-Ying Niu, Zheng-Liang Li, Zheng-En Song, Zheng-Jun Quan, Xi-Cun Wang, Guo-Ren Yue, Yi Pan. PEG-SO₃H as an efficient and reusable catalyst for chemoselective synthesis of 1,1-diacetates[J]. Chinese Chemical Letters, ;2013, 24(2): 140-142. shu

PEG-SO₃H as an efficient and reusable catalyst for chemoselective synthesis of 1,1-diacetates

1.
a Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities, College of Chemistry and Chemical Engineering, Hexi University, Zhangye 734000, China;
2.
b Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;
3.
c School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: Jun-Ke Wang,
Received Date: 20 November 2012
Available Online: 21 December 2012
Fund Project: This work was financially supported by Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities (No. XZ1011) (No. XZ1011) the President's Funds of Hexi University (No. XZ-2009-9) (No. XZ-2009-9)the National Natural Science Foundation of China (No. 21262010). (No. 21262010)

An efficient and convenient procedure of the synthesis of 1,1-diacetates from aromatic aldehydes and acetic anhydride under mild and solvent-free conditions at room temperature, in the presence of PEG-SO₃H is reported. PEG-SO₃H acts as a catalyst and can be recovered and reused eight times without apparent loss of its catalytic activity.
- Chemoselectivity,
- 1,1-Diacetate,
- PEG-SO₃H,
- Solvent-free
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

PEG-SO3H as an efficient and reusable catalyst for chemoselective synthesis of 1,1-diacetates

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通讯作者: 陈斌, bchen63@163.com

PEG-SO₃H as an efficient and reusable catalyst for chemoselective synthesis of 1,1-diacetates