Citation: Ke Dong, Jian-Xin Pu, Xue Du, Xiao-Nian Li, Han-Dong Sun. Two new guaianolide-type sesquiterpenoids from Kadsura interior[J]. Chinese Chemical Letters, ;2013, 24(2): 111-113. shu

Two new guaianolide-type sesquiterpenoids from Kadsura interior

1.
State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650204, China

Corresponding author: Jian-Xin Pu, Han-Dong Sun,
Received Date: 22 November 2012
Available Online: 26 December 2012
Fund Project:

Two new guaianolide-type sesquiterpenoids, 4β,9β-dihydroxy-1α,5α-H-guaia-6,10(14)-dien (1) and 4β,9β,10α-trihydroxy-1α,5α-H-guaia-6-en (2), along with four known sesquiterpenoids (3a, 3b, 4 and 5), were isolated from Kadsura interior. Their structures and configurations were elucidated by spectroscopicmethods including 2D-NMR and HR-MS techniques. Compounds 3a and 3b were obtained as a pair of enantiomers, and their structure and absolute configuration were established from their extensive NMR spectra and by single-crystal X-ray analysis.
- Kadsura interior,
- 4β,9β-Dihydroxy-1α,5α-H-guaia-6,10(14)-dien,
- 4β,9β,10α-Trihydroxy-1α,5α-H-guaia-6-en,
- X-ray technique
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沈阳化工大学材料科学与工程学院沈阳 110142