Citation: Chang-Zhi Zhao, Jun-Yu Liang, Xiao-Lei Gu, Hui Liu. Simultaneous determination of dihydroxybenzene isomers utilizing a thiadiazole film electrode[J]. Chinese Chemical Letters, ;2014, 25(2): 370-374. shu

Simultaneous determination of dihydroxybenzene isomers utilizing a thiadiazole film electrode

1.
College of Chemistry & Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, China

Corresponding author: Chang-Zhi Zhao,
Received Date: 28 August 2013
Available Online: 25 October 2013

The present study reports a sensitive electro-analytical method for the simultaneous determination of dihydroxybenzene isomers by using a thiadiazole film electrode, which was readily prepared by electropolymerization of 2,5-dimercapto-1,3,4-thiadiazole on a glassy carbon electrode with cyclic voltammetry. The functionalized electrode has a distinguishable and sensitive response to dihydroxybenzene isomers. Under the optimized conditions, the linear stripping peak currents showed good linear relationships with hydroquinone, catechol and resorcinol at concentration ranges 0.50-120, 0.50-110 and 1.00-110 μmol/L, and the detection limits are 0.1, 0.1 and 0.3 μmol/L, respectively. The proposed method is applicable to the simultaneous determination of dihydroxybenzene isomers in real samples with the relative standard deviations of less than 5.7% and the recovery rates of 95.6%-106%. The constructed electrode is characterized by simple preparation, good selectivity, and high sensitivity advantages.
- Electrochemical analysis,
- Dihydroxybenzene isomers,
- 2,5-Dimercapto-1,3,4-thiadiazole,
- Electropolymerization
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沈阳化工大学材料科学与工程学院沈阳 110142