Citation: Shun-Yang Yu, Yan-Cang Li, Tao Xiong, Qun Yuan, Yong-Ming Liu, Zhong-Yi Yuan, Yi Xiao. A ladder conjugated polymer transducer for solid-contact Cu²⁺-selective electrodes[J]. Chinese Chemical Letters, ;2014, 25(2): 364-366. shu

A ladder conjugated polymer transducer for solid-contact Cu²⁺-selective electrodes

Shun-Yang Yu ^a,, ,
Yan-Cang Li ^a,c ,
Tao Xiong ^b,, ,
Qun Yuan ^a,c ,
Yong-Ming Liu ^c ,
Zhong-Yi Yuan ^d ,
Yi Xiao ^d

1.
a Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research (YIC), Chinese Academy of Sciences(CAS), Shandong Provincial Key Laboratory of Coastal Environmental Processes, YICCAS, Yantai 264003, China;
2.
b Physical Science and Technical College, Dalian University, Dalian 116622, China;
3.
c Chemistry and Chemical Engineering College, Yantai University, Yantai 264005, China;
4.
d State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China

Corresponding author: Shun-Yang Yu, Tao Xiong,
Received Date: 19 July 2013
Available Online: 14 October 2013
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21107134) (No. 21107134) Chinese Academy of Sciences (No. KZCX2-YW-JS208) (No. KZCX2-YW-JS208)the Taishan Scholar Program of Shandong Province. (No. JQ200814)

In recent years, there has been a pronounced interest in solid-contact ion-selective electrodes (SC-ISEs), with emphasis on the use of conducting polymers as ion-to-electron transducer. In this work, a ladder conjugated polymer, thieno[3,2-b]thiophene (LCPT), was investigated in fabricating Cu²⁺-selective electrodes for the first time. The resulting electrodes were characterized by electrochemical impedance spectroscopy (EIS), chronopotentiometry, and the water layer test. Results proved that the active LCPT facilitates the ion-to-electron transduction, and avoids the detrimental aqueous layer formed at the interface of SC-ISEs.
- Ladder polymer,
- Solid contact,
- Ion-selective electrode,
- Copper
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沈阳化工大学材料科学与工程学院沈阳 110142

A ladder conjugated polymer transducer for solid-contact Cu2+-selective electrodes

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通讯作者: 陈斌, bchen63@163.com

A ladder conjugated polymer transducer for solid-contact Cu²⁺-selective electrodes