Advanced Search

Citation: Hamid Tajizadegan, Mehdi Rashidzadeh, Majid Jafari, Reza Ebrahimi-Kahrizsangi. Novel ZnO-Al2O3 composite particles as sorbent for low temperature H2S removal[J]. Chinese Chemical Letters, ;2013, 24(2): 167-169. shu

Novel ZnO-Al2O3 composite particles as sorbent for low temperature H2S removal

  • a Department of Materials Engineering, Najafabad Branch, Islamic Azad University, P.

    a Department of Materials Engineering, Najafabad Branch, Islamic Azad University, P.O. Box 517, Isfahan, Iran;

  • b Catalysis & Nanotechnology Research Division, Research Institute of Petroleum Industry (RIPI), P.

    b Catalysis & Nanotechnology Research Division, Research Institute of Petroleum Industry (RIPI), P.O. Box 14665-137, Tehran, Iran

  • Corresponding author: Hamid Tajizadegan, 
  • Received Date: 28 September 2012
    Available Online: 24 December 2012

  • ZnO-Al2O3 composite particles composed of ZnO nanosheets (thickness of 40-80 nm) on alumina particles were prepared by heterogeneous precipitation method using bayerite seed particles. The asprepared composite particles were characterized in terms of crystal structure,morphology, surface area and pore volume. The composite particles were used as sorbent for H2S adsorption at low temperature, and were compared with pure ZnO sorbent. The composite sorbent showed a greater sulfur adsorption capacity (0.052 g/g) than pure form of ZnO (0.028 g/g). This significant improvement was mainly attributed to higher surface area, more pore volume and unique morphology in nanoscale, which were also obtained by low cost presented method in this work for synthesis of ZnO sorbent supported on alumina particles.
  • 加载中
    1. [1]

      [1] D. Stirling, The Sulfur Problem: Cleaning up Industrial Feedstocks, The Royal Society of Chemistry, Cambridge, 2000.

    2. [2]

      [2] C. Li, Z.S. Yu, S.M. Fang, et al., Fabrication and gas sensing property of honeycomblike ZnO, Chin. Chem. Lett. 19 (2008) 599-603.

    3. [3]

      [3] J. Skrzypski, I. Bezverkhyy, O. Heintz, J.P. Bellat, Low temperature H2S removal with metal-doped nanostructure ZnO sorbents: study of the origin of enhanced reactivity in Cu-containing materials, Ind. Eng. Chem. Res. 50 (2011) 5714-5722.

    4. [4]

      [4] I. Rosso, C. Galletti, M. Bizzi, G. Saracco, V. Specchia, Zinc oxide sorbents for the removal of hydrogen sulfide from syngas, Ind. Eng. Chem. Res. 42 (2003) 1688-1697.

    5. [5]

      [5] Y.J. Lee, N.K. Park, G.B. Han, et al., The preparation and desulfurization of nano-size ZnO by a matrix-assisted method for the removal of low concentration of sulfur compounds, Curr. Appl. Phys. 8 (2008) 746-751.

    6. [6]

      [6] T.J. Lee, I.H. Cho, N.K. Park, Desulfurization using ZnO nanostructure prepared by matrix assisted method, Korean J. Chem. Eng. 26 (2009) 582-586.

    7. [7]

      [7] R. Habibia, A.M. Rashidib, J.T. Daryana, A.M. Ali Zadeh, Study of the rod-like and spherical nano-ZnO morphology on H2S removal from natural gas, Appl. Surf. Sci. 257 (2010) 434-439.

    8. [8]

      [8] I.I. Novochinskii, C.H. Song, X. Ma, et al., Low temperature H2S removal from steam-containing gas mixtures with ZnO for fuel cell application: 1. ZnO particles and extrudates, Energy Fuels 18 (2004) 576-583.

    9. [9]

      [9] G. Liua, Z.H. Huanga, F. Kang, Preparation of ZnO/SiO2 gel composites and their performance of H2S removal at room temperature, J. Hazard. Mater. 215-216 (2012) 166-172.

    10. [10]

      [10] X. Wang, T. Sun, J. Yang, L. Zhao, J. Jia, Low-temperature H2S removal from gas streams with SBA-15 supported ZnO nanoparticles, Chem. Eng. J. 142 (2008) 48-55.

    11. [11]

      [11] L. Chen, J. Shen, Effect of resorcinol formaldehyde resin gel on the preparation of Co/SiO2 catalysts for Fischer-Tropsch synthesis, Chin. J. Catal. 33 (2012) 621-628.

    12. [12]

      [12] Qiherima, H. Li, H. Yuan, Y. Zhang, G. Xu, Effect of alumina support on the formation of the active phase of selective hydrodesulfurization catalysts Co-Mo/Al2O3, Chin. J. Catal. 32 (2011) 240-249.

    13. [13]

      [13] Qiherima, H. Yuan, H.F. Li, Y.H. Zhang, G.T. Xu, Investigation on the active phase of Co/Mo catalyst for selective HDS by low temperature in situ FT-IR, Chin. Chem. Lett. 22 (2011) 366-369.

    14. [14]

      [14] K. Wefers, C. Misra, Oxides and Hydroxides of Aluminum, Alcoa Research Laboratories, Pennsylvania, 1987.

    15. [15]

      [15] C. Xu, J. Sun, B. Zhao, Q. Liu, On the study of KF/Zn(Al)O catalyst for biodiesel production from vegetable oil, Appl. Catal. B 99 (2010) 111-117.

    16. [16]

      [16] M. Mozibur Rahman, M.K.R. Khan, M. Rafiqul Islam, et al., Effect of Al doping on structural, electrical, optical and photoluminescence properties of nano-structural ZnO thin films, J. Mater. Sci. Technol. 28 (2012) 329-335.

  • 加载中
    1. [1]

      Shangqian Zhang , Jiaxuan Li , Xuan Hu , Zelong Chen , Junliang Dong , Chenhao Hu , Shuang Chao , Yinghua Lv , Yuxin Pei , Zhichao Pei . H2S and NIR light-driven nanomotors induce disulfidptosis for targeted anticancer therapy by enhancing disruption of tumor metabolic symbiosis. Chinese Chemical Letters, 2025, 36(1): 110314-. doi: 10.1016/j.cclet.2024.110314

    2. [2]

      Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490

    3. [3]

      Jia-Mei Qin , Xue Li , Wei Lang , Fu-Hao Zhang , Qian-Yong Cao . An AIEgen nano-assembly for simultaneous detection of ATP and H2S. Chinese Chemical Letters, 2024, 35(6): 108925-. doi: 10.1016/j.cclet.2023.108925

    4. [4]

      You Wu ,  Chang Cheng ,  Kezhen Qi ,  Bei Cheng ,  Jianjun Zhang ,  Jiaguo Yu ,  Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027

    5. [5]

      Yudi Cheng , Xiao Wang , Jiao Chen , Zihan Zhang , Jiadong Ou , Mengyao She , Fulin Chen , Jianli Li . A near-infrared fluorescent probe for visualizing transformation pathway of Cys/Hcy and H2S and its applications in living system. Chinese Chemical Letters, 2024, 35(5): 109156-. doi: 10.1016/j.cclet.2023.109156

    6. [6]

      Dongmei Yao , Junsheng Zheng , Liming Jin , Xiaomin Meng , Zize Zhan , Runlin Fan , Cong Feng , Pingwen Ming . Effect of surface oxidation on the interfacial and mechanical properties in graphite/epoxy composites composite bipolar plates. Chinese Chemical Letters, 2024, 35(11): 109382-. doi: 10.1016/j.cclet.2023.109382

    7. [7]

      Asif Hassan Raza ,  Shumail Farhan ,  Zhixian Yu ,  Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020

    8. [8]

      Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co3O4 sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO2 reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064

    9. [9]

      Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co2P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265

    10. [10]

      Fei ZHOU , Xiaolin JIA . Co3O4/TiO2 composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236

    11. [11]

      Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NOx reduction with improved N2 selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132

    12. [12]

      Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H2O2 production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526

    13. [13]

      Dong-Ling Kuang ,  Song Chen ,  Shaoru Chen ,  Yong-Jie Liao ,  Ning Li ,  Lai-Hon Chung ,  Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301

    14. [14]

      Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H2O2 photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251

    15. [15]

      Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350

    16. [16]

      Qinghong Pan , Huafang Zhang , Qiaoling Liu , Donghong Huang , Da-Peng Yang , Tianjia Jiang , Shuyang Sun , Xiangrong Chen . A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification. Chinese Chemical Letters, 2025, 36(1): 110169-. doi: 10.1016/j.cclet.2024.110169

    17. [17]

      Ping Wang ,  Tianbao Zhang ,  Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328

    18. [18]

      Bin Fang , Jiaqi Yang , Limin Wang , Haoqin Li , Jiaying Guo , Jiaxin Zhang , Qingyuan Guo , Bo Peng , Kedi Liu , Miaomiao Xi , Hua Bai , Li Fu , Lin Li . A mitochondria-targeted H2S-activatable fluorogenic probe for tracking hepatic ischemia-reperfusion injury. Chinese Chemical Letters, 2024, 35(6): 108913-. doi: 10.1016/j.cclet.2023.108913

    19. [19]

      Bicheng Zhu ,  Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327

    20. [20]

      Rui Liu ,  Jinbo Pang ,  Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(665)
  • HTML views(7)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return