Citation: Li LI, Peng LIANG, Yu LIU. Synthesis of A Novel Bridged Bis(β-cyclodextrin)s Possessing Phenan-throline Tether and Its Molecular Binding Ability with Dyes[J]. Chinese Chemical Letters, ;2003, 14(1): 9-12. shu

Synthesis of A Novel Bridged Bis(β-cyclodextrin)s Possessing Phenan-throline Tether and Its Molecular Binding Ability with Dyes

Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 5 April 2002

Fund Project: Tianjin Natural Science Foundalion (No.013613511) and the Foundation of Ministry of Education, which are gratefully acknowledged.This work was supported by the National Natural Science Foundalion (No.29992590-8 and 29972029) of China

A novel β-cyclodextrin dimer bearing 2, 9-diformyl-1, 10-phenanthroline tether 4 has been synthesized and its inclusion complexation behavior with two triangular model substrates(RhB and BG) has been investigated through fluorcseence and ultraviolet spectrometry. The result obtained indicated that novel bridged bis(β-cyclodcxtrin)s could significantly enhance the original molecular binding ability of native β-cyclodextrin by coopcrative binding of two hydrophobie cavities.
- Bis(β-cyclodextrin)s,
- inclusion complexation,
- dye,
- binding ability
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