Citation: Shu Xia CAO, Jian Chen ZHANG, Jun XU, Xin Cheng LIAO, Yu Fen ZHAO. Analysis of Hydrolysis Reaction of N-Phosphoryl Phenylalanine by HPLC-ESI-MS/MS[J]. Chinese Chemical Letters, ;2004, 15(7): 817-820. shu

Analysis of Hydrolysis Reaction of N-Phosphoryl Phenylalanine by HPLC-ESI-MS/MS

1.
The Key Laboratory of Chemical Biology, Department of Chemistry, Zhengzhou University, Zhengzhou 450052;
2.
The Key Laboratory for Bioorganic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Department of Chemistry School of Life Science and Engineering, Tsinghua University, Beijing 100084

Received Date: 6 July 2003

Hydrolysis procedure of N-phosphoryl phenylalanine (DIPP-Phe) was studied by HPLC-ESI-MS/MS. The results showed that (HO)(i-PrO)P(O)Phe was the main intermediate and the hydrolysis of DIPP-Phe also occurred through a penta-coordinate transition state.
- N-Phosphoryl amino acids,
- hydrolysis reaction,
- HPLC-ESI-MS
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