Citation: WAN Xinhua, TU Yingfeng, ZHANG Dong, ZHOU Qifeng. "LIVING" FREE RADICAL SYNTHESIS OF NOVEL RODCOIL DIBLOCK COPOLYMERS WITH POLYSTYRENE AND MESOGEN-JACKETED LIQUID CRYSTAL POLYMER SEGMENTS*[J]. Chinese Journal of Polymer Science, ;1998, 16(4): 377-380. shu

"LIVING" FREE RADICAL SYNTHESIS OF NOVEL RODCOIL DIBLOCK COPOLYMERS WITH POLYSTYRENE AND MESOGEN-JACKETED LIQUID CRYSTAL POLYMER SEGMENTS*

Received Date: 14 September 1998

The synthesis of rod-coil diblock copolymers was achieved for the firsttime by TEMPO-mediated "living" free radical polymerization of styrene and 2,5-bis[(4-methoxyphenyl)oxycarbonyl]styrene(MPCS). The block architecture of the two diblockcopolymers thus prepared, MPCS-b-St(5400/2400) and MPCS-b-St(10800/8700), was con-firmed by GPC, DSC studies and the formation of multimolecular micelles.
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