Citation: Xiao Guang XIE, Xue Mei GAO, Shi Xi LUI, Huai CAO, Shu Shan DAI. The Nature of Bonding in PtC and PtN[J]. Chinese Chemical Letters, ;2001, 12(6): 541-544. shu

The Nature of Bonding in PtC and PtN

1.
Department of Chemistry, Yunnan University Kunming 650091;
2.
Modern Biological Center, Yunnan University Kunming 650091

Received Date: 31 October 2000

The nature of bonding in the title compounds has been studied by using CASSCF and FOCI techniques. The ground states of PtC and PtN are found to be ¹Σ⁺ and ²Π state arising primarily from:…1σ²2σ²1π⁴1δ⁴3σ² and …1σ²2σ²1π⁴1δ⁴3σ²2π¹ configuration respectively and both of which form triple bond (one σ, two πbonds), but the bond of PtC is much stronger than that of PtN.
- PtC and PtN,
- nature of bonding,
- molecular constants,
- CASSCF,
- FOCI.
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