Citation: Guo Dong ZHENG, Qing DING, Qing Da AN, Xi Zhang CAO. ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYTZED BY METALLOPORPHYRINS(Ⅳ)--EFFECT OF VARIOUS FACTORS ON ELECTROCARBOXYLATION[J]. Chinese Chemical Letters, ;1992, 3(5): 357-358. shu

ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYTZED BY METALLOPORPHYRINS(Ⅳ)--EFFECT OF VARIOUS FACTORS ON ELECTROCARBOXYLATION

a Department of Chemistry Jilin University Changchun 130023;
b To whom all correspondence should be addressed;
c Present adress;Dalian Institute of Light Industry

Received Date: 18 December 1991

Fund Project: This work is supported by the National Natural Science Foundation of China.

The effects of various factors on the electrocarboxylation of organic compounds withcarbon dioxide catalyzed by metalloporphyrin are studied.The optimal potential of electrocar-boxylation is-1.6 V(vs.SCE).A weak protic solvent methanol can enhance catalytic activity.Tetrabutylammonium iodide is the best one of five electrolytes.The yields and current efficienciesof electrocarboxylation are increased slowly as the concentration of catalyst increases
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