Citation: Zhi Quan ZHAO, Li Zeng PENG, Yu Lin LI. Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction[J]. Chinese Chemical Letters, ;2005, 16(3): 290-292. shu

Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction

1.
Lunan Pharmaceutical Co., Ltd., Linyi, Shandong 276003;
2.
National Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 16 January 2004

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Grant No. 20072012).

The phenomenon of migration of the silyl groups from α-oxygen to β-oxygen in sodium aldol reaction was observed for the first time in this paper.
- Silyl migration,
- α-silyloxy ketone,
- aldol reaction.
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