Citation: Jue CHENG, Yi ZHENG, Wan Tai YANG. Surface Grafting of Phenolic Resole onto LDPE Films[J]. Chinese Chemical Letters, ;2006, 17(8): 1133-1136. shu

Surface Grafting of Phenolic Resole onto LDPE Films

Jue CHENG ^1,2, ,
Yi ZHENG ^1,2 ,
Wan Tai YANG ^1,2

1.
Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing 100029;
2.
College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029

Received Date: 18 January 2006

Low density polyethylene film surface-grafted phenolic resole was prepared by a sequential processes. Firstly, acrylic acid was grafted to the surface of low density polyethylene by photo-grafting. Secondly, the carboxylic groups in poly(acrylic acid) chains were transferred to sulfonic groups by the reaction of carboxylic groups with sulfanilic acid. Finally, a thin layer of phenolic resole was cured onto the surface of low density polyethylene. The grafting process was characterized by FTIR-ATR and gravimetric analysis. A possible model was proposed to interpret the experimental results.
- Surface grafting,
- low density polyethylene film,
- sulfanilic acid,
- phenolic resole
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