Citation: Xin Jian ZHAO, Hua Rong ZHAO, Xian HUANG. Samarium(Ⅱ) Diiodide Induced Polarity Inversion of π-Allyl Palladium Complexes: The Formation of Allylic Selenides[J]. Chinese Chemical Letters, ;2002, 13(5): 396-397. shu

Samarium(Ⅱ) Diiodide Induced Polarity Inversion of π-Allyl Palladium Complexes: The Formation of Allylic Selenides

1.
Zhejiang Institute of Calibaration and Testing for Technical Superision, Hangzhou 310013;
2.
Department of Chemistry, Zhejiang University, Hangzhou 310027

Received Date: 17 August 2001

Allylic acetates were reduced with Pd(0)-SmI₂ in the presence of ArSeBr to form corresponding allylic selenides in good yields.
- Allyl acetates,
- allylic selenides,
- arylselenenyl bromides,
- palladium complexes,
- polarity inversion
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