Citation: Fan Zhi KONG, Yan Hua WANG, Zi Lin JIN. Hydroformylation of Oleyl Alcohol Catalyzed by Rh-OPGPP Complex[J]. Chinese Chemical Letters, ;2002, 13(6): 497-498. shu

Hydroformylation of Oleyl Alcohol Catalyzed by Rh-OPGPP Complex

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Received Date: 17 September 2001

Fund Project: The authors are grateful to the financial support from the National Natural Science Foundation of China (Grant no. 29906001).

Polyether-tailored phosphite modified rhodium complex formed in situ was highly active in the hydroformylation of oleyl alcohol in nonaqueous phosphite/heptane system where the phosphite acted both as the ligand and the second phase. This catalyst was easily separated by simple decantation and can be used for five times with only a slight decrease in activity.
- Phosphite,
- hydroformylation,
- oleyl alcohol,
- nonaqueous biphasic catalysis
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