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Prathima Kamath, M.Srinivasan, V.N.Krishnamurthy. CURE CHARACTERISTICS OF HYDROXYL TERMINATED POLYBUTADIENE PREPOLYMER WITH BLOCKED TOLUENE DIISOCYANATE-Ⅰ[J]. Chinese Journal of Polymer Science,
;1993, 11(3): 284-291.
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Controlled release of TDI and hence the cure characteristics of several blocked TDI with HTPB are reported. The reactions were followed through viscosity measurements as a function of time and temperature under the catalytic influence of triethylamine. The effect of nature of substituents present on the end capping substrate, temperature, solvent, basicity of catalyst and kinetics thereon have been studied.
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