Citation: An Qi CHEN, Christine L. WILLIS. Stereoselective Functionalization at C-2 and C-3 of the Gibberellin via an Intramolecular Free Radical Cyclization Approach[J]. Chinese Chemical Letters, ;2001, 12(5): 397-398. shu

Stereoselective Functionalization at C-2 and C-3 of the Gibberellin via an Intramolecular Free Radical Cyclization Approach

An Qi CHEN ¹ ,
Christine L. WILLIS ²

1.
Department of Chemistry, Xiamen University, Xiamen, 361005;
2.
School of Chemistry, University of Bristol, Bristol, UK BS8 1TS

Received Date: 16 October 2000

Fund Project: This work is supported by the State Education Department under Scientific Research Foundation for Returned Overseas Chinese Scholars.

Stereoselective functionalization at C-2 and C-3 of the gibberellin skeleton was achieved via an intramolecular free radical cyclization approach using a tethered C-19 halomethyl ester as the radical precursor.
- Gibberellin,
- lactonization,
- free radical cyclization.
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