Citation: Xiang Kai FU, Xue Bing MA. Synthesis of a New Type of Amphilic and Water-soluble Tertiary Phosphine Ligands Substituted by an Ethoxylated Phosphonic Acid Chain and Their Palladium Complexes[J]. Chinese Chemical Letters, ;2002, 13(9): 839-842. shu

Synthesis of a New Type of Amphilic and Water-soluble Tertiary Phosphine Ligands Substituted by an Ethoxylated Phosphonic Acid Chain and Their Palladium Complexes

College of Chemistry and Chemical Engineering, Southwest-China Normal University, Chongqing 400715

Received Date: 1 December 2001

The highly water-soluble phosphine ligands Na₂O₃PCH₂CH₂NH(CH₂CH₂O)_nCH₂CH₂N(CH₂PPh₂)₂ (n=1,2,3) were prepared by a new and simple route under mild conditions in goodyield; the palladium (Ⅱ) complexes of the ligands 3a~c with 2:1 or 4:1-PPh₂ to Pd²⁺ molar ratiowere also prepared and characterized.
- Water-soluble,
- diphenylphosphinomethyl,
- phosphine ligands,
- palladium complexes,
- synthesis
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