Citation: James Kammert, Jisue Moon, Zili Wu. A review of the interactions between ceria and H₂ and the applications to selective hydrogenation of alkynes[J]. Chinese Journal of Catalysis, ;2020, 41(6): 901-914. doi: S1872-2067(19)63509-6 shu

A review of the interactions between ceria and H₂ and the applications to selective hydrogenation of alkynes

Chemical Science Division and Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA

Received Date: 29 September 2019
Revised Date: 21 October 2019

Cerium oxide (ceria) has found a wide variety of applications in catalysis including as a catalyst, a modifier, or a support, largely thanks to its robust redox properties and versatile acid-base function. While it is often utilized for oxidation reactions, ceria has recently attracted intense research interest for its unusual ability to selectively hydrogenate alkynes to alkenes. The intriguing hydrogenation ability of ceria has sparked renewed research efforts to understand how pure ceria works as a hydrogenation catalyst. In this review, recent advances in both experimental and computational studies of ceria are summarized, focusing on the interaction of ceria with H₂ and in hydrogenation reactions. Significant insights from various studies including in situ spectroscopy/microscopy and theoretic modeling of ceria in hydrogen-involved reactions are discussed, which shed light on the origin of the hydrogenation ability of ceria and the reaction mechanisms involved in ceria-catalyzed alkyne hydrogenation. Ways to further improve both the mechanistic understanding and catalytic performance of ceria-based materials for hydrogenation reactions are proposed at the end in the summary and outlook section.
- Ceria,
- Redox,
- Hydrogen,
- Hydrogenation,
- Hydride,
- Mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142

A review of the interactions between ceria and H2 and the applications to selective hydrogenation of alkynes

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通讯作者: 陈斌, bchen63@163.com

A review of the interactions between ceria and H₂ and the applications to selective hydrogenation of alkynes