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Citation: Linquan Bao, Chengcheng Zhao, Shenggang Li, Yan Zhu. Benzalaniline from nitrobenzene and benzaldehyde catalyzed efficiently by an atomically precise palladium nanocluster[J]. Chinese Journal of Catalysis, ;2019, 40(10): 1499-1504. doi: S1872-2067(19)63423-6 shu

Benzalaniline from nitrobenzene and benzaldehyde catalyzed efficiently by an atomically precise palladium nanocluster

a Key Laboratory of Mesoscopic Chemistry, MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, Jiangsu, China;
b Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

Received Date: 18 June 2019
Revised Date: 16 July 2019

Fund Project: We acknowledge financial supports from National Natural Science Foundation of China (21773109, 91845104).

Nanoclusters with a precise number of atoms may exhibit unique and often unexpected catalytic properties. Here, we report an atomically precise Pd₃ nanocluster as an efficient catalyst, whose catalytic performance differs remarkably from typical Pd nanoparticle catalysts, with excellent reactivity and selectivity in the one-pot synthesis of benzalaniline from nitrobenzene and benzaldehyde. We anticipate that our work will serve as a starting point for the catalytic applications of these tiny atomically precise nanoclusters in green chemistry for the one-pot syntheses of fine chemicals.
- Nanoclusters,
- Palladium,
- Reductive amidation,
- Selectivity,
- Activity
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