Citation: Shelly Kelly, Wharton Sinkler, Lijun Xu, Sergio Sanchez, Cem Akatay, Haiyan Wang, John Qianjun Chen. Advanced characterization for industrial catalysis applications[J]. Chinese Journal of Catalysis, ;2019, 40(11): 1637-1654. doi: S1872-2067(19)63372-3 shu

Advanced characterization for industrial catalysis applications

Honeywell UOP, 25 E Algonquin Road, Des Plaines, IL 60016, Unites States of America

Received Date: 31 January 2019
Revised Date: 28 March 2019

The interplay between analytical technique and industrial practice has been central in the development of catalytic materials for processing petroleum. This article presents reviews of key aspects of two of the most important classes of catalytic materials:noble-metal Pt nanoparticles (NPs) on alumina, which are the basis of catalytic reforming; and layered sulfides of Mo and W, which catalyze hydrogenation and hetero-atom removal in hydroprocessing. The state of understanding of Pt cluster growth and resulting structures, as developed using X-ray absorption spectroscopy and STEM, is reviewed. Influences of both Pt reduction temperature in hydrogen gas, and oxidizing pretreatment conditions prior to Pt reduction, are considered. Recent work by the present authors on Pt NP structure evolution is presented in the context of the previous work. A review is subsequently presented of layered sulfide based NPs, summarizing contributions from a range of analytical techniques. Work on active site structures of sulfide NPs is reviewed, focusing particularly on the critical interactions of active edge sites with sulfur and hydrogen in chemisorption, physisorption, and spillover interactions. New temperature programmed reduction (TPR) results are presented for supported and unsupported sulfide NPs. Structural changes in TPR of alumina-supported MoS2 are investigated using extended X-ray absorption fine structure and density functional theory modeling, and are determined to arise from removal of identifiable edge-site sulfur species.
- Catalysis fundamental,
- Platinum,
- Metal sulfides,
- Catalytic reforming,
- Hydroprocessing
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沈阳化工大学材料科学与工程学院沈阳 110142