Citation: Shenzhou Li, Jianyun Liu, Shuo Duan, Tanyuan Wang, Qing Li. Tuning the oxygen evolution electrocatalysis on NiFe-layered double hydroxides via sulfur doping[J]. Chinese Journal of Catalysis, ;2020, 41(5): 847-852. doi: S1872-2067(19)63356-5 shu

Tuning the oxygen evolution electrocatalysis on NiFe-layered double hydroxides via sulfur doping

State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China

Received Date: 14 October 2019
Revised Date: 18 November 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (21603078, 21705052, 51602223).

We report a facile way to prepare sulfur (S) doped Ni_4/5Fe_1/5-layered double hydroxide (LDH) electrocatalysts for oxygen evolution reaction (OER). The influence of S doping amount on the OER activity of the resulted NiFe-LDHs was studied and the optimal surface S content was ca. 0.43 at%. The developed S-doped NiFe-LDH exhibits excellent OER catalyst activity in 1.0 M KOH with overpotential of only 257 mV at the current density of 10 mA cm^-2. Moreover, the catalyst could maintain high activity after 30 h stability test. The high activity of the S-doped NiFe-LDH catalysts may originate from the synergistic effect between S and the Fe sites. This work provides a simple but efficient way to improve the OER performance of transition metal oxides/(oxy)hydroxides.
- Oxygen evolution,
- Electrocatalysis,
- Layered double hydroxides,
- Sulfur doping,
- Water splitting
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
1. [1]
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