Citation: Xinjiang Cui, Xingchao Dai, Annette-Enrica Surkus, Kathrin Junge, Carsten Kreyenschulte, Giovanni Agostini, Nils Rockstroh, Matthias Beller. Zinc single atoms on N-doped carbon: An efficient and stable catalyst for CO₂ fixation and conversion[J]. Chinese Journal of Catalysis, ;2019, 40(11): 1679-1685. doi: S1872-2067(19)63316-4 shu

Zinc single atoms on N-doped carbon: An efficient and stable catalyst for CO₂ fixation and conversion

a Leibniz-Institut für Katalyse e.V. Albert-Einstein-Str. 29a, 18059 Rostock, Germany;
b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China

Received Date: 21 January 2019
Revised Date: 27 January 2019

Fund Project: This work was supported by the National Key R&D Program of China (2017YFA0403103), the state of Mecklenburg-Vorpommern and the Bundesministerium fü

The cycloaddition of epoxides and carbon dioxide represents a straightforward and atom-efficient method for synthesis of cyclic carbonates and utilization of CO₂. So far, homogeneous metal complexes have been mainly applied for such transformations. Here, we describe the synthesis of novel heterogeneous Zn-based catalysts, which were conveniently prepared by pyrolysis of an active-carbon-supported phenanthroline-ligated Zn(OAc)₂ complex. Detail structural characterizations proved the existence of single zinc sites in the active material. Compared to a Zn-based nanoparticle (Zn-NP) catalyst, the resulting single metal atom catalyst (SAC) displayed improved activity and stability for the cycloaddition of epoxides. By applying the optimal catalyst, a variety of carbonates were successfully obtained in high yields with good functional group tolerance.
- Heterogeneous catalysis,
- Single atom catalyst,
- Zinc,
- Carbon dioxide,
- Cycloaddition,
- Carbonate
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沈阳化工大学材料科学与工程学院沈阳 110142

Zinc single atoms on N-doped carbon: An efficient and stable catalyst for CO2 fixation and conversion

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通讯作者: 陈斌, bchen63@163.com

Zinc single atoms on N-doped carbon: An efficient and stable catalyst for CO₂ fixation and conversion