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Citation: GAO Meixiang, LUO Dong, MAO Liqiu, YIN Dulin. Oxidation of Cyclohexylamine to Cyclohexanone Oxime Catalyzed by Al₂O₃-SiO₂[J]. Chinese Journal of Applied Chemistry, ;2013, 30(1): 28-31. doi: DOI:10.3724/SP.J.1095.2013.20072 shu

Oxidation of Cyclohexylamine to Cyclohexanone Oxime Catalyzed by Al₂O₃-SiO₂

1.
Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081, China

Corresponding author: MAO Liqiu,
Received Date: 1 March 2012
Available Online: 10 May 2012
Fund Project: 国家自然科学基金资助项目(20976043) (20976043)

The oxidation of cyclohexylamine catalyzed by Al₂O₃-SiO₂ catalyst was carried out under mild conditions.The effects of solvent amount,catalyst amount,reaction time and reaction temperature on the reaction were investigated.Under the conditions of V(acetonitrile):V(cyclohexylamine)=3:1,31.0% mass fraction of catalyst,reaction temperature of 75℃,and reaction time of 5 h,the conversion of cyclohexylamine reaches up to 100% and the selectivity for cyclohexanone oxime is 83.6%.A reaction mechanism is proposed.
- cyclohexylamine,
- oxidation,
- cyclohexanone oxime
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Oxidation of Cyclohexylamine to Cyclohexanone Oxime Catalyzed by Al2O3-SiO2

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Oxidation of Cyclohexylamine to Cyclohexanone Oxime Catalyzed by Al₂O₃-SiO₂