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Citation: WANG Kaikai, ZHANG Qixian, LI Yafeng, NIU Li. Synthesis and Photoluminescence of the Derivatives of Symmetrical Bi-oxadiazoles Containing Azobenzene[J]. Chinese Journal of Applied Chemistry, ;2013, 30(1): 48-53. doi: DOI:10.3724/SP.J.1095.2013.20052 shu

Synthesis and Photoluminescence of the Derivatives of Symmetrical Bi-oxadiazoles Containing Azobenzene

WANG Kaikai ^a ,
ZHANG Qixian ^b ,
LI Yafeng ^a,, ,
NIU Li ^b,c,,

1.
a School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China;
2.
b Engineering Laboratory for Modern Analytical Techniques, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
3.
c Changzhou Institute of Energy Storage Materials and Devices, Changzhou 213002, China

Corresponding author: LI Yafeng, NIU Li,
Received Date: 21 February 2012
Available Online: 26 March 2012
Fund Project: 吉林省科技厅(20080518)项目资助 (20080518)常州市科技项目(CJ20110016) (CJ20110016)

A series of derivatives of symmetrircal bi-oxadiazoles containing azobenzene was synthesized.Their molecular structures were determined by IR and ¹H NMR spectroscopies.The effect of azobenzene on the photoluminescence of oxadiazole derivatives was carefully studied by fluorescence spectra.The emission peaks of F₃,F₆ and F₁₀ are bimodal,at 348,356 nm and 345,357 nm and 345,357 nm,respectively,attributed to the oxadiazole groups of bi-oxadiazoles.The introduction of azobenzene has less impact on the emission maximum peak of oxadiazole derivatives F_n in solution,but the luminous intensity of oxadiazole derivatives F_n decreases.This is mainly because of the intramolecular electronic energy transfer between the azobenzene groups and the oxadiazole groups in the process of photoexcitation.
- azobenzene,
- oxadiazole,
- synthesis,
- photoluminescence
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