Citation: Chen Weixing, Wang Ting, Zhang Yunfei, Li Shuying, Zhou Hongwei, Jia Yanlin, Jin Xilang. A Seminaphthorhodafluor-Based Fluorescent Probe for H₂S Detection and Its Application[J]. Chinese Journal of Organic Chemistry, ;2020, 40(9): 2956-2962. doi: 10.6023/cjoc202006001 shu

A Seminaphthorhodafluor-Based Fluorescent Probe for H₂S Detection and Its Application

a.
School of Material and Chemical Engineering, Xi'an Technological University, Xi'an 710021
b.
College of Materials Science and Engineering, Central South University, Changsha, 410083

Corresponding author: Jia Yanlin, jiayanlin@126.com Jin Xilang, jinxilang_911@163.com
Received Date: 2 June 2020
Revised Date: 24 June 2020
Available Online: 15 July 2020
Fund Project: National Natural Science Foundation of China 51603164the Natural Science Foundation Research Project of Shaanxi Province 2018JQ2015Project supported by the National Natural Science Foundation of China (Nos. 51603164, 21807085), and the Natural Science Foundation Research Project of Shaanxi Province (No. 2018JQ2015)National Natural Science Foundation of China 21807085

Figures(10)

A novel colorimetric and long-wavelength fluorescent probe (SR) based on seminaphthorhodafluor dye was designed and synthesized, which was used to detect H₂S through the thiolysis reaction of dinitrophenyl ether and unique OFF-ON mechanism based on the spiro-ring of probe SR. The fluorescent intensity (635 nm) and absorbance (590 nm) changes exhibited an excellent linear relationship with the H₂S concentration ranging from 2.00 to 10.00 μmol/L and the detection limits were 0.50 and 1.00 μmol/L, respectively. Ions interference experiments showed that probe SR had an excellent anti-interference ability and could be used to detect H₂S in complex systems. The probe SR was further exploited for filter paper, hydrogel and Hela cells for the rapid and convenient detection of H₂S, which extended the applications of fluorescent probes for the detection of H₂S in chemistry and the environment.
- long-wavelength,
- fluorescence,
- hydrogel,
- H₂S,
- probe
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通讯作者: 陈斌, bchen63@163.com

A Seminaphthorhodafluor-Based Fluorescent Probe for H₂S Detection and Its Application