Citation: Lei Mengmeng, Zhou Qihang, Yang Li, Xu Zhihong, Yang Fengling. A Highly Sensitive and Selective "Off-On" Fluorescent Probe for Cu²⁺ Based on Rhodamine B Hydrazone[J]. Chinese Journal of Organic Chemistry, ;2020, 40(9): 2798-2803. doi: 10.6023/cjoc202005084 shu

A Highly Sensitive and Selective "Off-On" Fluorescent Probe for Cu²⁺ Based on Rhodamine B Hydrazone

Lei Mengmeng ^a,b ,
Zhou Qihang ^a,b ,
Yang Li ^a,b ,
Xu Zhihong ^a,b,, ,
Yang Fengling ^a,,

a.
College of Chemistry, Zhengzhou University, Zhengzhou 450001
b.
College of Chemical and Materials Engineering, Xuchang University, Xuchang, Henan 461000

Corresponding author: Xu Zhihong, xuzhihong1980@yahoo.com Yang Fengling, yangfengling2005@yahoo.com.cn
Received Date: 29 May 2020
Revised Date: 2 July 2020
Available Online: 8 July 2020
Fund Project: the Joint Program for Fostering Talents of National Natural Science Foundation of China and Henan Province U1304202the Science and Technology Project of Henan Province 192102310295the Key Program in Universities of Henan Province 19A150046the Key Program of Xuchang City 2019-JC-02Project supported by the Joint Program for Fostering Talents of National Natural Science Foundation of China and Henan Province (No. U1304202), the Program for Science and Technology Innovation Talents in Universities of Henan Province (No. 15HASTIT002), the Science and Technology Project of Henan Province (No. 192102310295), the Key Program in Universities of Henan Province (No. 19A150046), and the Key Program of Xuchang City (No. 2019-JC-02)the Program for Science and Technology Innovation Talents in Universities of Henan Province 15HASTIT002

Figures(6)

Ethyl 5-formyl-3, 4-dimethyl-pyrrole-2-carboxylate and rhodamine B hydrazide were used to synthesize a rhodamine derivative R1. Notably, the as-synthesized R1 displayed great sensitivity and selectivity, which was utilized to be an off-on fluorescence probe for Cu²⁺ detectionin mediums that contained water. Besides, the Cu²⁺ ions limit of detection (LOD) was 0.201 μmol·L^-1, and R1 was able to sense Cu²⁺ by "naked-eye" according to the change in color to pink from colorless. In addition, Cu²⁺ detection was assessed within the actual water samples for testing the probe actual application.
- fluorescent probe,
- rhodamine,
- pyrrole,
- Cu²⁺
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A Highly Sensitive and Selective "Off-On" Fluorescent Probe for Cu2+ Based on Rhodamine B Hydrazone

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通讯作者: 陈斌, bchen63@163.com

A Highly Sensitive and Selective "Off-On" Fluorescent Probe for Cu²⁺ Based on Rhodamine B Hydrazone