Citation: Teng Qiaoling, Xu Lulu, Cheng Dongping, Xu Xiaoliang. Synthesis of 10-Phenanthrenol Derivatives via Visible Light Catalyzed Itramolecular Cycloaromatization[J]. Chinese Journal of Organic Chemistry, ;2020, 40(12): 4258-4266. doi: 10.6023/cjoc202005077 shu

Synthesis of 10-Phenanthrenol Derivatives via Visible Light Catalyzed Itramolecular Cycloaromatization

a.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
b.
College of Pharmaceutical, Zhejiang University of Technology, Hangzhou 310014

Corresponding author: Cheng Dongping, chengdp@zjut.edu.cn Xu Xiaoliang, xuxiaoliang@zjut.edu.cn
Received Date: 28 May 2020
Revised Date: 21 July 2020
Available Online: 5 August 2020
Fund Project: the National Natural Science Foundation of China 21602197the Zhejiang Provincial Natural Science Foundation LY18B020018Project supported by the Zhejiang Provincial Natural Science Foundation (Nos. LY18B020018, LY15B020004) and the National Natural Science Foundation of China (No. 21602197)the Zhejiang Provincial Natural Science Foundation LY15B020004

Figures(2)

Phenanthrene derivatives play an important role in pharmaceutical chemistry and material science. Due to its advantages of green, mild reaction conditions and great application potential, visible light catalysis has become a powerful tool in organic synthesis. In this paper, under the catalysis of photocatalyst Ir[dF(CF₃)ppy]₂(dtbbpy)PF₆, a series of 10-phenanthrenol derivatives were synthesized from 2-arylbenzoyl acetate derivatives in moderate to good yields through intramolecular cycloaromatization. In addition, the plausible reaction mechanism was also proposed.
- visible-light photocatalysis,
- radical reaction,
- intramolecular cycloaromatization,
- phenanthrenols
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