Citation: Wu Jieqing, Gu Jiefan, Chen Qinrui, Ma Hongfei, Li Yufeng. Ni(Ⅱ)-Catalyzed Oxidative Coupling of Arenes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(9): 2772-2777. doi: 10.6023/cjoc202005073 shu

Ni(Ⅱ)-Catalyzed Oxidative Coupling of Arenes

College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816

Corresponding author: Li Yufeng, yufengli@njtech.edu.cn
Received Date: 26 May 2020
Revised Date: 19 June 2020
Available Online: 15 July 2020

Figures(2)

A protocol for the synthesis of bibenzyls via nickel acetylacetonate-catalyzed coupling of arenes was devloped using di-tert-butylperoxide as the oxidant with the asistance of 1, 4-diazabicyclo[2.2.2]octane (DABCO). The process tolerated to different substrates, among of which, isopropylbenzene provided the most satisfactory yield of bibenzyls in 73% yield. The cross-coupling of arenes with cycloalkanes was also realized under the optimal reaction conditions but accompanied with the self-coupling of substrates. The method could effectively restrain the formation of alcohol, aldehyde, acid.
- arene,
- coupling,
- di-tert-butylperoxide,
- nickel(Ⅱ) acetylacetonate,
- bibenzyl
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