Citation: Jiang Qian, Wang Zhonglong, Li Mingxin, Yang Yiqin, Xu Xu, Xu Haijun, Wang Shifa. Nopinone-Based Difluoroboron β-Diketonate Complex: Aggregation-Induced Emission and Solvatochromism[J]. Chinese Journal of Organic Chemistry, ;2020, 40(12): 4290-4297. doi: 10.6023/cjoc202005049 shu

Nopinone-Based Difluoroboron β-Diketonate Complex: Aggregation-Induced Emission and Solvatochromism

Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Light Industry and Food, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037

Corresponding author: Wang Shifa, wangshifa65@163.com
Received Date: 19 May 2020
Revised Date: 23 June 2020
Available Online: 22 July 2020
Fund Project: Project supported by the National Natural Science Foundation of China (No. 31470592)the National Natural Science Foundation of China 31470592

Figures(9)

Three difluoroboron (BF₂) β-diketonates 2a~2c including different aromatic ring systems were synthesized from nopinone which was the derivative of renewable natural β-pinene. In the solid state, compounds 2a~2c exhibit different fluorescent colors. Compounds 2b and 2c showed the positive solvatochromism phenomenon, and they have different fluorescence colors in different polar solvents. In addition, compounds 2b and 2c have significant aggregation-induced emission (AIE) effect. Compounds 2b and 2c were made into electroluminescent devices Ⅰ and Ⅱ, and device Ⅰ and Ⅱ emit green light and yellow light, respectively. The results indicate that compounds 2b and 2c have good application prospects as organic solid luminescent materials.
- nopinone,
- β-diketonate,
- aggregation-induced emission (AIE) effect,
- solvatochromism
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