Citation: Jin Jikang, Xia Huimin, Zhang Fenglian, Wang Yifeng. Lewis-Base Boryl Radicals Enabled Borylation, Radical Catalysis and Reduction Reactions[J]. Chinese Journal of Organic Chemistry, ;2020, 40(8): 2185-2194. doi: 10.6023/cjoc202005017 shu

Lewis-Base Boryl Radicals Enabled Borylation, Radical Catalysis and Reduction Reactions

Department of Chemistry, University of Science and Technology of China, Hefei 230026

Corresponding author: Wang Yifeng, yfwangzj@ustc.edu.cn
Received Date: 7 May 2020
Revised Date: 19 May 2020
Available Online: 27 May 2020
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21672195, 21702201, 21971226) and the Fundamental Research Funds for the Central Universities (No. WK2060190082)the Fundamental Research Funds for the Central Universities WK2060190082the National Natural Science Foundation of China 21702201the National Natural Science Foundation of China 21672195the National Natural Science Foundation of China 21971226

Figures(11)

Free radical reactions represent an efficient and significant tool to construct organic molecules by taking advantages of the high-efficiency, remarkable selectivity and good functional groups tolerance. Lewis-base boryl radicals are a class of species that possess unique structures and chemical reactivity, and a variety of synthetic applications have been developed. This account summarizes the research advances in this research field mainly contributed by our group. The results include Lewis-based boryl radicals enabled borylation reactions, Lewis-based boryl radicals-catalyzed new reactions, and Lewis-based boryl radicals promoted reduction reactions. These reactions feature mild reaction conditions, good functional groups compatibility, high yields, and excellent chemo-, regio-, and stereo-selectivities.
- Lewis-base boryl radicals,
- radical borylation reactions,
- radical catalysis,
- radical reduction reactions,
- free radical chemistry
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沈阳化工大学材料科学与工程学院沈阳 110142