Citation: Liu Zilin, Zhang Xiaojie, Zhang Heng, Jiang Hui, Zhao Xuemei, Shi Linlin, Zhu Xinju, Hao Xinqi, Song Maoping. Phathalocyanine Metal Complexes (M=Fe, Co, and Cu) Catalyzed Aerobic Oxidation of 2-Amino-benzyl Alcohols to Access Quinazolines and Quinolines[J]. Chinese Journal of Organic Chemistry, ;2020, 40(9): 2755-2763. doi: 10.6023/cjoc202003068 shu

Phathalocyanine Metal Complexes (M=Fe, Co, and Cu) Catalyzed Aerobic Oxidation of 2-Amino-benzyl Alcohols to Access Quinazolines and Quinolines

College of Chemistry, Zhengzhou University, Zhengzhou 450001

Corresponding author: Zhao Xuemei, zxm@zzu.edu.cn Shi Linlin, slinlinzzu@163.com
Received Date: 31 March 2020
Revised Date: 27 May 2020
Available Online: 12 June 2020
Fund Project: the National Natural Science Foundation of China 21803059the National Natural Science Foundation of China U1904212the National Natural Science Foundation of China 21672192Project supported by the National Natural Science Foundation of China (Nos. 21672192, 21803059, U1904212, 21929101)the National Natural Science Foundation of China 21929101

Figures(4)

Phathalocyanine metal complexes catalyzed oxidative condensation of 2-aminobenzyl alcohols with nitriles and ketones has been developed under air to afford quinazolines and quinolines, respectively. After systematic investigation, iron(Ⅱ) phathalocyanine displayed higher catalytic activity in quinazoline synthesis and copper(Ⅱ) phathalocyanine showed higher efficiency in quinoline preparation. Under the optimized conditions, various nitriles and ketones were well adaptted to give the corresponding products in good yields.
- phathalocyanine metal complexes,
- quinazolines,
- quinolines,
- aerobic oxidation
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