Citation: Wang Xiangyang, Xu Xuetao, Wang Zhenhua, Fang Ping, Mei Tiansheng. Advances in Asymmetric Organotransition Metal-Catalyzed Electrochemistry[J]. Chinese Journal of Organic Chemistry, ;2020, 40(11): 3738-3747. doi: 10.6023/cjoc202003022 shu

Advances in Asymmetric Organotransition Metal-Catalyzed Electrochemistry

a.
School of Biotechnology and Health Science, Wuyi University, Jiangmen, Guangzhou 529020
b.
State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Fang Ping, pfang@sioc.ac.cn Mei Tiansheng, mei7900@sioc.ac.cn
Received Date: 9 March 2020
Revised Date: 24 May 2020
Available Online: 25 May 2020
Fund Project: Project supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB20000000), the National Natural Science Foundation of China (Nos. 91956112, 21572245, 21772222, 21772220), and the Program of Shanghai Science and Technology Committee of Shanghai (Nos. 17JC1401200, 18JC1415600)the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the National Natural Science Foundation of China 21772220the National Natural Science Foundation of China 91956112the National Natural Science Foundation of China 21572245the Program of Shanghai Science and Technology Committee of Shanghai 18JC1415600the Program of Shanghai Science and Technology Committee of Shanghai 17JC1401200the National Natural Science Foundation of China 21772222

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The recent developments in asymmetric organotransition metal-catalyzed electrochemistry (AOMCE) are summarized. AOMCE processes can be divided into oxidative and reductive variants. In terms of oxidations, asymmetric functionalization of olefins, oxidative kinetic resolution of secondary alcohols or aldehydes, and asymmetric C—H functionalization reactions have been developed. Reductive processes discussed include asymmetric electrochemical carboxylation with carbon dioxide, asymmetric electrochemical decarboxylation, and asymmetric reductive coupling reactions. The combination of chiral ligands, transition-metal catalysts, and electrochemistry provides a novel angle by which to address the longstanding fundamental challenge of stereoinduction in traditional electrochemical organic synthesis.
- asymmetric organotransition metal-catalyzed electrochemistry,
- electrochemical organic synthesis,
- asymmetric catalysis
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